2696-95-9

Basic information

• Product Name: Cyclohexane, nitroso-
• CAS NO: 2696-95-9
• Molecular Formula: C6H11NO
• Molecular Weight: 113.159
• Mol File: 2696-95-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Cyclohexane, nitroso-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexane, nitroso-(2696-95-9)
• EPA Substance Registry System: Cyclohexane, nitroso-(2696-95-9)

Safety Data

• Hazardous Substances Data: 2696-95-9(Hazardous Substances Data)

Usage

General Description

Cyclohexane, nitroso- is a chemical compound with the formula C6H11NO. It is a colorless liquid with a faint, nitroso-amine odor, and it is used as a solvent and in the production of rubber chemicals and pharmaceuticals. It is also known to be highly flammable and may react violently with oxidizing agents and strong acids. Cyclohexane, nitroso- has been found to have reproductive and developmental toxicity in animal studies and is considered a potential occupational hazard. It is important to handle this chemical with care and follow proper safety protocols when working with it.

Upstream product

• 110-82-7 cyclohexane 
• 2211-64-5 N-cyclohexyl-hydroxylamine 

Downstream Products

• 1646-26-0 1-(benzo[b]furan-2-yl)ethanone 
• 2286-03-5 N-Cyclohexyl-N'-fluordiimid-N-oxid 
• 4359-62-0 N,N'-dicyclohexylhydrazine 

Relevant articles and documents

Unexpected Insertion of Nitrogen into a C-C Bond: Access to 2,3-Disubstituted Quinazolinone Scaffolds

A novel, practical, highly efficient, and transition metal free nitrogen insertion reaction for the synthesis of 2,3-disubstituted quinazolinone derivatives was developed. Diverse functionalized 3-indolinone-2-carboxylates and nitrosoarenes with a wide range of substituted nitrosobenzenes, nitrosopyridines, dibenzofuranyl, or dibenzothienyl nitroso compounds worked smoothly to give 2,3-disubstituted quinazolinone derivatives in good to excellent yields (69-98%). A gram-scale reaction was achieved, and an afloqualone analogue was synthesized under the mild reaction conditions.

Mild and selective catalytic oxidation of organic substrates by a carbon nanotube-rhodium nanohybrid

A heterogeneous catalyst was assembled by stabilization of rhodium nanoparticles on carbon nanotubes. The nanohybrid was used for the catalytic aerobic oxidation of diverse substrates such as hydroquinones, hydroxylamines, silanes, hydrazines and thiols, at room temperature. The system proved very efficient on the investigated substrates and demonstrated high selectivity.

A convenient synthesis of aryl nitroso compounds

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