270921-38-5

Basic information

• Product Name: (4-methylphenyl)methyl carbonate
• Synonyms: (4-methylphenyl)methyl carbonate
• CAS NO: 270921-38-5
• Molecular Weight: 180.203
• Mol File: 270921-38-5.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: (4-methylphenyl)methyl carbonate(CAS DataBase Reference)
• NIST Chemistry Reference: (4-methylphenyl)methyl carbonate(270921-38-5)
• EPA Substance Registry System: (4-methylphenyl)methyl carbonate(270921-38-5)

Safety Data

• Hazardous Substances Data: 270921-38-5(Hazardous Substances Data)

Upstream product

• 589-18-4 4-Methylbenzyl alcohol 
• 616-38-6 carbonic acid dimethyl ester 
• 67-56-1 methanol 
• 124-38-9 carbon dioxide 
• 79-22-1 methyl chloroformate 

Downstream Products

• 1159517-68-6 2-(4-methylbenzyl)benzo[d]oxazole 
• 1216910-94-9 2-[2-(4-methylphenyl)-1-phenylethyl]benzoxazole 
• 622-47-9 4-tolylacetic acid 
• 620-83-7 1-methyl-4-(phenylmethyl)benzene 
• 21895-17-0 p-(2-methylbenzyl)toluene 
• 170789-13-6 1-methyl-4-(4-(trifluoromethyl)benzyl)benzene 
• 22865-60-7 1-(4-methoxybenzyl)-4-methylbenzene 
• 61692-85-1 1-methyl-4-(3-phenyl-2-propyn-1-yl) benzene 
• 82291-79-0 2-acetylamino-2-(4-methylbenzyl)malonic acid diethyl ester 
• 53144-71-1 4-methylphenylmethyl diphenylphosphine oxide 
• 17105-64-5 dimethyl <(4-methylphenyl)methyl>phosphonate 

Relevant articles and documents

Light-induced synthesis of unsymmetrical organic carbonates from alcohols, methanol and CO2under ambient conditions

The present work describes the first visible light-assisted, metal-free and organic base 1,1,3,3-tetramethyl guanidine (TMG) mediated synthesis of unsymmetrical methyl aryl/alkyl carbonates from the reaction of alcohols, methanol, and CO2 in high to excel

Cleavage of C–C and C–O Bonds to Form C–C Bonds: Direct Cross-Coupling between Acetylenic Alcohols and Benzylic Carbonates

A palladium-catalyzed cross-coupling reaction between C(sp) and C(sp3) centers was achieved in excellent yields via C–C bond cleavage and C–O bond cleavage. This procedure uses relatively stable acetylenic alcohols as reactants instead of unsta

A general Pd-catalyzed α- And γ-benzylation of aldehydes for the formation of quaternary centers

A palladium-catalyzed benzylation of α-branched aldehydes has been developed using benzyl methyl carbonates. The method gives access to congested quaternary centers in the vicinity of one of the most sensitive carbonyl functionalities and displays unprecedented generality with respect to both coupling partners. Evidence for the direct involvement of a Pd-η3-benzyl intermediate is provided. Extension of this strategy to the γ-benzylation of α,β-unsaturated aldehydes is further demonstrated.