27286-84-6Relevant articles and documents
Synthesis of Fulvene Vinyl Ethers by Gold Catalysis
Ahrens, Alexander,Dreuw, Andreas,Hashmi, A. Stephen K.,Hoffmann, Marvin,Lustosa, Danilo M.,Pourkaveh, Raheleh,Rominger, Frank,Rudolph, Matthias,Schwarz, Julia
supporting information, (2020/04/20)
Gold-catalyzed cyclization of 1,5-diynes with ketones as reagents and solvent provides diversely substituted vinyl ethers under mild conditions. The regioselectivity of such gold-catalyzed cyclizations is usually controlled by the scaffold of the diyne. H
5-Exo-dig radical cyclization of enediynes: The first synthesis of tin-substituted benzofulvenes
Kovalenko, Serguei V.,Peabody, Scott,Manoharan, Mariappan,Clark, Ronald J.,Alabugin, Igor V.
, p. 2457 - 2460 (2007/10/03)
(Equation Presented) Bu3Sn-mediated 5-exo-dig radical cyclization of diaryl enediynes provides a mild and efficient approach to tin-substituted fulvenes. Further synthetic opportunities opened by this process and general factors responsible for