2733-79-1

Basic information

• Product Name: Naphthalene, 1,2-dihydro-1,1-dimethyl-
• CAS NO: 2733-79-1
• Molecular Formula: C12H14
• Molecular Weight: 158.243
• Mol File: 2733-79-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Naphthalene, 1,2-dihydro-1,1-dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Naphthalene, 1,2-dihydro-1,1-dimethyl-(2733-79-1)
• EPA Substance Registry System: Naphthalene, 1,2-dihydro-1,1-dimethyl-(2733-79-1)

Safety Data

• Hazardous Substances Data: 2733-79-1(Hazardous Substances Data)

Upstream product

• 3123-97-5 dihydro-5,5-dimethyl-2(3H)-furanone 

Downstream Products

• 1610344-92-7 1-((1R,2R)-2-hydroxy-4,4-dimethyl-1,2,3,4-tetrahydronaphthalen-1-yl)-3-(4-methyl-1-phenyl-3-(quinuclidin-3-yloxy)-1H-pyrazol-5-yl)urea 
• 148967-82-2 3,3-dimethyl-1a,2,3,7b-tetrahydronaphtho[1,2-b]oxirene 
• 573-98-8 dimethyl-1,2 naphtalene 
• 40075-94-3 2'-Isopropylphenylallen 
• 21919-45-9 1-Allyl-2-isopropenyl-benzene 

Relevant articles and documents

Half-open ferrocenes and ruthenocenes containing an edge-bridged open indenyl ligand

Potassium 1,1-dimethyl-1,2-dihydronaphthalenide, K(eboInd) (1), was synthesized in three steps from 4,4-dimethyl-1-tetralone and used for the synthesis of half-open metallocenes containing an edge-bridged open indenyl ligand (eboInd). Successive treatment of [(THF)FeI2] with Li(C 5Me5) and 1 at low temperatures afforded [(η5-C5Me5)Fe(η5-eboInd)] (2), whereas [(η5-C5Me5) Ru(η5-eboInd)] (3) was synthesized by reaction of 1 with [(C 5Me5)RuCl]4. Both compounds reacted with CO and 2,6-dimethylphenyl isocyanide (CN-o-Xy) to form [(η5-C 5Me5)M(η3-eboInd)L] (4: M = Fe, L = CO; 5: M = Ru, L = CO; 6: M = Fe, L = CN-o-Xy; 7: M = Ru, L = CN-o-Xy), in which the eboInd ligand has undergone an η5-to-η3 hapticity conversion. In contrast, the N-heterocyclic carbene 1,3,4,5- tetramethylimidazolin-2-ylidene (IMe) only reacted with the ruthenocene derivative 3 to give [(η5-C5Me5) Ru(η3-eboInd)(IMe)] (8). The molecular structures of 2-7 were determined by X-ray diffraction analysis. None of the iron-ruthenium pairs are isotypic.