273747-77-6

Basic information

• Product Name: C₂₈H₂₆N₄S₂O₂CoCH₃
• CAS NO: 273747-77-6
• Molecular Weight: 588.7
• Mol File: 273747-77-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₈H₂₆N₄S₂O₂CoCH₃(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₈H₂₆N₄S₂O₂CoCH₃(273747-77-6)
• EPA Substance Registry System: C₂₈H₂₆N₄S₂O₂CoCH₃(273747-77-6)

Safety Data

• Hazardous Substances Data: 273747-77-6(Hazardous Substances Data)

Upstream product

• 23642-14-0 CoMe(pyridine)(dimethylglyoxime(-1H))2 
• 273747-81-2 C₂₈H₂₆N₄S₂O₂Co^(1-) 

Relevant articles and documents

Electrochemical methylation of a chelate anionic NiI complex with methylcobaloxime. Partial modeling of the action mechanism of the active center of acetyl-CoA synthase

Electrochemically generated anions of Co and Ni chelate complexes can be alkylated with BunBr, BunI, and (dmgH)2CoMe (dmgH is the dimethylglyoximate anion). Unlike the anionic Co complexes, the anionic Ni complex cannot be alkylated with BunBr; however, it reacts with stronger alkylating agents (BunI and (dmgH)2CoMe). It is assumed that the electrochemical alkylation of the Ni complex with (dmgH)2CoMe can serve as a model for alkylation occurring in biological synthesis of acetyl coenzyme A. Reactions of some Co chelate anions with BunI can proceed via the reduction of the latter.