27376-59-6Relevant articles and documents
One-Pot Controlled Reduction of Conjugated Amides by Sequential Double Hydrosilylation Catalyzed by an Iridium(III) Metallacycle
Agbossou-Niedercorn, Francine,Corre, Yann,Djukic, Jean-Pierre,Kalocsai, Dorottya,Michon, Christophe,Nagyházi, Márton,Rysak, Vincent,Trivelli, Xavier
supporting information, p. 6212 - 6220 (2020/10/02)
A single and accessible cationic iridiumIII metallacycle effectively catalyzes the one-pot sequential double hydrosilylation of challenging α,β-unsaturated secondary and tertiary amides to afford, in a controlled and straightforward way, the co
Nickel-Catalyzed Reduction of Secondary and Tertiary Amides
Simmons, Bryan J.,Hoffmann, Marie,Hwang, Jaeyeon,Jackl, Moritz K.,Garg, Neil K.
supporting information, p. 1910 - 1913 (2017/04/11)
The nickel-catalyzed reduction of secondary and tertiary amides to give amine products is reported. The transformation is tolerant of extensive variation with respect to the amide substrate, proceeds in the presence of esters and epimerizable stereocenters, and can be used to achieve the reduction of lactams. Moreover, this methodology provides a simple tactic for accessing medicinally relevant α-deuterated amines.
Coordination chemistry and catalytic activity of ruthenium(II) complexes containing a phospha-macrocyclic ligand
Lee, Chun-Chin,Huang, Hsiao-Ching,Liu, Shiuh-Tzung,Liu, Yi-Hung,Peng, Shie-Ming,Chen, Jwu-Ting
, p. 1024 - 1029 (2013/06/05)
Substitution of [RuCl2(CO)3(THF)], [RuCl 2(dmso)4] and [RuCl2(PPh3) 3] with a macrocyclic ligand, 2,3,4,5,6,7,8,9-octahydro-1,9-diphenyl- 1H-5,1,9-benzazadiphosphacyclo undecine (11-P2NH), provided [Ru(11-P2NH)Cl2(CO)] (3), [Ru(11-P2NH)Cl 2(dmso)] (4) and [Ru(11-P2NH)Cl2(CH 3CN)] (5), respectively. These complexes were characterized by elemental analyses as well as NMR spectroscopy. The structure of 3 was further confirmed by X-ray diffraction analysis. The octahedral geometry around the ruthenium center is in agreement with the Werner's "coordination" bonding concepts. The chelate rings of the macrocycle toward Ru(II) center adopting into chair conformations were revealed. Furthermore, these ruthenium complexes were found to be active for N-alkylation of dibenzylamine with alcohols.