27499-64-5Relevant articles and documents
Highly phosphorescent organopalladium(ii) complexes with metal-metal-to-ligand charge-transfer excited states in fluid solutions
Lin, Jinqiang,Zou, Chao,Zhang, Xiaobao,Gao, Qin,Suo, Sa,Zhuo, Qihang,Chang, Xiaoyong,Xie, Mo,Lu, Wei
, p. 10417 - 10421 (2019)
Dinuclear pincer-type cyclometalated Pd(ii) complexes with foldable diacetylide ligands show crystallographically determined intramolecular Pd?Pd contacts of 3.203-3.380 ?. In deoxygenated fluid solutions, these Pd(ii) complexes are highly phosphorescent
Chirality Sensing with Stereodynamic Biphenolate Zinc Complexes
Bentley, Keith W.,De Los Santos, Zeus A.,Weiss, Mary J.,Wolf, Christian
, p. 700 - 707 (2015/10/12)
Two bidentate ligands consisting of a fluxional polyarylacetylene framework with terminal phenol groups were synthesized. Reaction with diethylzinc gives stereodynamic complexes that undergo distinct asymmetric transformation of the first kind upon binding of chiral amines and amino alcohols. The substrate-to-ligand chirality imprinting at the zinc coordination sphere results in characteristic circular dichroism signals that can be used for direct enantiomeric excess (ee) analysis. This chemosensing approach bears potential for high-throughput ee screening with small sample amounts and reduced solvent waste compared to traditional high-performance liquid chromatography methods. Chirality 27:700-707, 2015.
Syntheses, optical properties and photoactivated insecticidal activities of cyclic arylethynylsilanes
Shao, Guang,Li, Yong,Yu, Huijuan,He, Ting,Jiang, Dingxin
scheme or table, p. 278 - 282 (2012/01/05)
Syntheses and optical properties of cyclic arylethynylsilanes containing one or two trialkyne pockets were described. Optical properties such as UV-vis spectra, photoluminescence and quantum yield based on these conjugated structural features were compare
