276870-78-1

Basic information

• Product Name: 2-Diazo-3-oxo-butyric acid (2R,3S,5R)-5-(6-amino-purin-9-yl)-2-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-3-yl ester
• CAS NO: 276870-78-1
• Molecular Weight: 599.721
• Mol File: 276870-78-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Diazo-3-oxo-butyric acid (2R,3S,5R)-5-(6-amino-purin-9-yl)-2-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-3-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Diazo-3-oxo-butyric acid (2R,3S,5R)-5-(6-amino-purin-9-yl)-2-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-3-yl ester(276870-78-1)
• EPA Substance Registry System: 2-Diazo-3-oxo-butyric acid (2R,3S,5R)-5-(6-amino-purin-9-yl)-2-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-3-yl ester(276870-78-1)

Safety Data

• Hazardous Substances Data: 276870-78-1(Hazardous Substances Data)

Upstream product

• 958-09-8 2'-deoxy-D-adenosine 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 24762-04-7 2-Diazo-3-oxo-butyric acid methyl ester 
• 129835-18-3 (2R,3S,5R)-5-(6-amino-9H-purin-9-yl)-2-(((tert-butyldiphenylsilyl)oxy)methyl)tetrahydrofuran-3-ol 

Relevant articles and documents

Diastereoselective synthesis of α-substituted-γ-butyrolactones of nucleosides via [1,5]-c,h insertion reactions of α-diazomalonates of nucleosides

Diastereoselective and regioselective [1,5]-C,H insertion reactions of 2'-deoxy-3'-diazomalonate nucleosides afforded τ-butyrolactones of nucleosides as chiral synthons for the preparation of 2'-C-branched nucleosides.