276882-25-8

Basic information

• Product Name: allyl-2-cyano-4-nitrobenzene
• Synonyms: allyl-2-cyano-4-nitrobenzene
• CAS NO: 276882-25-8
• Molecular Weight: 188.186
• Mol File: 276882-25-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: allyl-2-cyano-4-nitrobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: allyl-2-cyano-4-nitrobenzene(276882-25-8)
• EPA Substance Registry System: allyl-2-cyano-4-nitrobenzene(276882-25-8)

Safety Data

• Hazardous Substances Data: 276882-25-8(Hazardous Substances Data)

Upstream product

• 17420-30-3 5-nitroanthranilonitrile 
• 106-95-6 allyl bromide 
• 540-80-7 tert.-butylnitrite 

Relevant articles and documents

Aromatic allylation via diazotization: Metal-free C-C bond formation

A new method for the synthesis of allyl aromatic compounds not involving any metal-containing reagent or catalyst has been developed. Arylamines substituted with a large number of different substituents were converted via diazotizative deamination with tert-butyl nitrite in allyl bromide and acetonitrile to the corresponding allyl aromatic compounds. The allylation reaction was found to be suitable for larger scale synthesis due to short reaction times, a nonextractive workup, and robustness toward moisture, air, and type of solvent.