27798-45-4

Basic information

• Product Name: 3-(4-TERT-BUTYLPHENYL)-1-PROPENE
• Synonyms: 3-(4-TERT-BUTYLPHENYL)-1-PROPENE
• CAS NO: 27798-45-4
• Molecular Formula: C₁₃H₁₈
• Molecular Weight: 174.28
• Mol File: 27798-45-4.mol
• Article Data: 27

Chemical Properties

• Boiling Point: 105°C 10,5mm
• Flash Point: 86.7°C
• Appearance: /
• Density: 0.869g/cm³
• Vapor Pressure: 0.103mmHg at 25°C
• Refractive Index: 1.495
• CAS DataBase Reference: 3-(4-TERT-BUTYLPHENYL)-1-PROPENE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(4-TERT-BUTYLPHENYL)-1-PROPENE(27798-45-4)
• EPA Substance Registry System: 3-(4-TERT-BUTYLPHENYL)-1-PROPENE(27798-45-4)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36/37/39
• Hazardous Substances Data: 27798-45-4(Hazardous Substances Data)

Usage

General Description

3-(4-tert-butylphenyl)-1-propene is a chemical compound with the formula C13H18. It is an organic compound classified as an alkene, which contains a benzene ring with a tert-butyl group attached to the fourth carbon atom and a propene group attached to the first carbon atom. 3-(4-TERT-BUTYLPHENYL)-1-PROPENE is used in the production of polymers and plastics, as well as in the synthesis of other organic compounds. It is also used as a reagent in organic chemistry reactions and as a precursor to various other chemicals. It is important to handle this chemical with care and in accordance with safety guidelines, as it can be hazardous if not handled properly.

InChI:InChI=1/C13H18/c1-5-6-11-7-9-12(10-8-11)13(2,3)4/h5,7-10H,1,6H2,2-4H3

Upstream product

• 3972-65-4 1-bromo-4-tert-butylbenzene 
• 106-95-6 allyl bromide 
• 253185-03-4 tert-butylbenzene 
• 762-72-1 allyl-trimethyl-silane 
• 35779-04-5 1-tert-butyl-4-iodobenzene 
• 173604-95-0 CH₂CHCH₂SnBr(N(Si(CH₃)3)2)2 
• 769-92-6 4-tert-Butylaniline 
• 52436-75-6 (4-tert-butylphenyl)diazonium tetrafluoroborate 
• 75-05-8 acetonitrile 
• 24850-33-7 allyltributylstanane 
• 107-05-1 3-chloroprop-1-ene 
• 591-87-7 Allyl acetate 
• 154318-75-9 4-tert-butylphenyl triflate 
• 1092390-58-3 sodium 1,1-dimethyl-1-(2-propen-1-yl)silanolate 

Downstream Products

• 1265015-19-7 (E)-3-(4-tert-butylphenyl)acrylic acid n-butyl ester 
• 1024039-12-0 2-(4-tert-butylphenyl)butyraldehyde 
• 62518-66-5 3-(4-tert-butylphenyl)propionaldehyde 
• 80-54-6 lilial 
• 211314-96-4 2-(4-(tert-butyl)phenyl)butanoic acid 
• 66735-04-4 4-(1,1-dimethylethyl)-α-methyl-benzenepropanoic acid 
• 24475-36-3 4-[4-(1,1-dimethylethyl)phenyl]butanoic acid 
• 117721-77-4 (E)-3-(4-(tert-butyl)phenyl)prop-2-en-1-ol 
• 1375536-67-6 (E)-2-(4-(4-(tert-butyl)phenyl)but-3-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 917114-13-7 2-(4-(tert-butyl)phenyl)quinoline 
• 1613403-39-6 (2E,4E)-methyl 5-(4-(tert-butyl)phenyl)-2-phenylpenta-2,4-dienoate 

Relevant articles and documents

Manganese catalyzed dehydrogenative silylation of alkenes: Direct access to allylsilanes

Dehydrogenative silylation of alkenes with silanes to produce allylsilanes is achieved through manganese catalysis with a wide scope of substrate tolerance. This transformation involves silane radicals initiated by manganese complex without additional oxidant additives. It offers a general, convenient and practical protocol with excellent functional group compatibility and gram-scale capacity for the modular synthesis of allylsilanes.

Exploiting the trifluoroethyl group as a precatalyst ligand in nickel-catalyzed Suzuki-type alkylations

We report herein the exploitment of the partially fluorinated trifluoroethyl as precatalyst ligands in nickel-catalyzed Suzuki-type alkylation and fluoroalkylation coupling reactions. Compared with the [LnNiII(aryl)(X)] precatalysts, the unique characters of bis-trifluoroethyl ligands imparted precatalyst [(bipy)Ni(CH2CF3)2] with bench-top stability, good solubilities in organic media and interesting catalytic activities. Preliminary mechanistic studies reveal that an eliminative extrusion of a vinylidene difluoride (VDF, CH2CF2) mask from [(bipy)Ni(CH2CF3)2] is a critical step for the initiation of a catalytic reaction.

Palladium-catalyzed allylic C-H oxidation under simple operation and mild conditions

We discovered an effective and simple system (Pd/BQ/air/r.t.) for making allylic alcohols through Pd-catalyzed allylic C-H bond functionalization. This approach exhibits advantages due to its simple operation, mild conditions, and environmentally benign features. By modifying reaction conditions, it can be suitable for preparing unsaturated aldehydes, allylic esters, ethers, and amines.