27922-90-3

Basic information

• Product Name: Ethanone, 1,2-bis(3,4-dimethoxyphenyl)-2-phenyl-
• CAS NO: 27922-90-3
• Molecular Formula: C24H24O5
• Molecular Weight: 392.452
• Mol File: 27922-90-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Ethanone, 1,2-bis(3,4-dimethoxyphenyl)-2-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1,2-bis(3,4-dimethoxyphenyl)-2-phenyl-(27922-90-3)
• EPA Substance Registry System: Ethanone, 1,2-bis(3,4-dimethoxyphenyl)-2-phenyl-(27922-90-3)

Safety Data

• Hazardous Substances Data: 27922-90-3(Hazardous Substances Data)

Upstream product

• 1131-62-0 1-(3,4-dimethoxyphenyl)ethanone 
• 108-86-1 bromobenzene 
• 4927-55-3 1,2-bis(3,4-dimethoxyphenyl)ethanone 
• 2859-78-1 4-Bromoveratrole 

Relevant articles and documents

PCP-Bis(phosphinite) pincer complexes: new homogeneous catalysts for α-arylation of ketones

Two new p-alkoxycarbonylated palladium bis(phosphinite) PCP pincer complexes are easily prepared and for the first time evaluated as homogeneous catalysts in α-arylation of ketone enolates. Apart from the total absence of phenyl-aryl exchange by-products and significantly low catalyst loadings, the general α-arylation protocols described in this letter feature not only a broad applicability to a range of ketones and aryl bromides with marked electronic and steric differences but also the possibility to generate mono-diarylated products.

Palladium-catalyzed arylation of ketone enolates: an expeditious entry to tamoxifen-related 1,2,2-triarylethanones.

[reaction: see text]. After a rigorous study on the effect of several catalytic systems, a simple, high yielding procedure for the preparation of 1,2,2-triarylethanones, skeletal analogues of tamoxifen, is presented. Apart from the economic and environmen