2800-96-6

Basic information

• Product Name: TIN(IV) ACETATE
• Synonyms: TETRAACETOXYTIN;TIN(IV) ACETATE;ACETIC ACID, TIN(IV) SALT;Tinacetate;Tin(IV) acetate, extra pure, 98%;TIN(IV) ACETATE, 98%, EXTRA PURE;Tetraacetic acid tin(IV) salt;Tin(IV) acetate, extra pure, 98% 5GR
• CAS NO: 2800-96-6
• Molecular Formula: C₄H₆O₄Sn
• Molecular Weight: 354.89
• EINECS: 604-604-1
• Product Categories: Micro/Nanoelectronics;Solution Deposition Precursors;Tin
• Mol File: 2800-96-6.mol
• Article Data: 5

Chemical Properties

• Melting Point: 232-233 °C(lit.)
• Flash Point: 40°C
• Appearance: White/Crystalline Powder
• Vapor Pressure: 13.9mmHg at 25°C
• Solubility: Soluble in acetone and benzene.
• Sensitive: Hygroscopic
• CAS DataBase Reference: TIN(IV) ACETATE(CAS DataBase Reference)
• NIST Chemistry Reference: TIN(IV) ACETATE(2800-96-6)
• EPA Substance Registry System: TIN(IV) ACETATE(2800-96-6)

Safety Data

• Hazard Codes: Xn
• Statements: 20/21/22
• Safety Statements: 36
• RIDADR: UN 3146 6.1/PG 3
• WGK Germany: 3
• TSCA: No
• Hazardous Substances Data: 2800-96-6(Hazardous Substances Data)

Usage

Description

Tin(IV) acetate, also known as stannic acetate, is a white crystalline powder with chemical properties that make it a versatile compound in various industries. It is a tin-based compound that is widely used for its unique properties and applications.

Uses

Used in Energy Storage Industry:
Tin(IV) acetate is used as a precursor for the preparation of tin-based oxides (Sn-Zn-P-O), which serve as negative electrodes in rechargeable lithium batteries. The application reason is that these oxides provide improved energy storage capacity and performance compared to traditional materials, making them a promising option for the development of advanced battery technologies.

InChI:InChI=1/4C2H4O2.Sn/c4*1-2(3)4;/h4*1H3,(H,3,4);/q;;;;+4/p-4

Upstream product

• 64-19-7 acetic acid 
• 595-90-4 tetraphenyltin(IV) 
• 108-24-7 acetic anhydride 
• 2273-51-0 diphenyltin(IV) oxide 
• 563-68-8 thallium(I) acetate 
• 7440-31-5 stannane 
• 26078-96-6 bis(cyclopentadienyl)tin(II) 
• 7440-31-5 tin 
• 22541-90-8 tin(II) 
• 14794-99-1 tin(II) bis(methoxide) 
• 71-50-1 acetate 

Downstream Products

• 110956-75-7 3-(4-chloro-5-cyclopentyloxy-2-fluorophenyl)-5-isopropylidene-1,3-oxazolidine-2,4-dione 
• 7440-31-5 tin 
• 597-64-8 tetraethyltin 
• 5697-00-7 1,4-diacetoxynaphthalene 
• 1907-13-7 acetoxytriethylstannane 
• 15522-00-6 bis{N-(P,P-diphosphinoyl)-P,P-diphenylphosphinimidato}tin 
• 151653-63-3 Sn(C₆H₅C(C(C₆H₅)HO)NNCSNH₂)2 
• 151653-62-2 Sn(CH₃COO)2(C₆H₅C(C(C₆H₅)HO)NNCSNH₂) 
• 105117-97-3 (CH₃CO₂)3Sn(SC₆H₄NC(CH₃)(C₆H₅)) 
• 105117-92-8 (CH₃CO₂)2Sn(SC₆H₄NC(CH₃)(C₆H₅))2 
• 105117-98-4 (CH₃CO₂)3Sn(SC₆H₄NCH(C₆H₅)) 
• 151653-58-6 Sn(CH₃COO)2(C₆H₅C(C(C₆H₅)HO)NNCONH₂) 
• 151653-59-7 Sn(C₆H₅C(C(C₆H₅)HO)NNCONH₂)2 

Relevant articles and documents

Crystal structure and chemical bonding in tin(II) acetate

Tin(II) acetate was prepared and its crystal structure was solved from X-ray powder diffraction data. Tin(II) acetate adopts a polymeric structure consisting of infinite Sn(CH3COO)2 chains running along the c-axis which are packed into groups of four. The acetate groups bridge the Sn atoms along the chains. The Sn atoms are asymmetrically surrounded by four oxygen atoms with two short Sn-O distances (2.170(6), 2.207(6) ?) and two longer ones (2.293(7), 2.372(8) ?). The coordination environment of the Sn atoms is completed up to a strongly distorted trigonal bipyramid SnO4E by the sterically active lone electron pair E. The coordination environment of the Sn atoms is virtually identical for Sn(CH3COO)2 in the gaseous and solid phase: the two short Sn-O bonds and the lone electron pair are located in the equatorial plane of the trigonal bipyramid and the two longer Sn-O bonds are directed towards the apical vertexes. Localization of the lone electron pair on Sn(II) was confirmed by electron localization function (ELF) analysis. The polymeric nature of the tin(II) acetate crystal structure was confirmed by a MALDI-TOF experiment.

Low melting point tin salt of carboxylic acid and method for producing the same

The present invention provides a low melting point tin salt of aliphatic monocarboxylic acid obtained by a process comprising, reacting an aliphatic monocarboxylic acid having 4 to 30 carbon atoms or its salt and an inorganic tin compound so as to prepare a tin salt of aliphatic monocarboxylic acid, and bringing the tin salt in contact with an oxygen supplying substance.

Method for the preparation of anhydrous tin-(IV)-carboxylates

A method is disclosed for the preparation of anhydrous tin-(IV)-carboxylate. Metallic tin or Sn-(II)-acetate is reacted with an excess of acetic acid anhydride under agitation and at temperatures of 50° to 150° C. Oxygen is passed through the reaction mixture or an oxygen yielding agent is added thereto. The tin-(IV)-acetate thus formed, which is useful, per se, is separated from the reaction mixture and further reacted with a carboxylic acid with more than four carbon atoms or an acid anhydride corresponding to said carboxylic acid. The reaction is carried out at temperatures of about 80° to 150° C. and the liberated acetic acid anhydride or acetic acid is removed by distillation under vacuum.