28049-00-5

Basic information

• Product Name: Benzenepropanoic acid, 3-phenyl-2-propynyl ester
• CAS NO: 28049-00-5
• Molecular Formula: C18H16O2
• Molecular Weight: 264.324
• Mol File: 28049-00-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzenepropanoic acid, 3-phenyl-2-propynyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenepropanoic acid, 3-phenyl-2-propynyl ester(28049-00-5)
• EPA Substance Registry System: Benzenepropanoic acid, 3-phenyl-2-propynyl ester(28049-00-5)

Safety Data

• Hazardous Substances Data: 28049-00-5(Hazardous Substances Data)

Upstream product

• 2579-22-8 Phenylpropargyl aldehyde 
• 22767-96-0 Benzyl 3-phenylpropionate 
• 103-25-3 3-phenylpropanoic acid methyl ester 
• 2021-28-5 ethyl dihydrocinnamate 
• 1504-58-1 3-Phenyl-2-propyn-1-ol 
• 501-52-0 3-Phenylpropionic acid 

Relevant articles and documents

Fluorous biphasic esterification directed towards ultimate atom efficiency

Aperfectly selective esterification that discriminates between primary and sterically hindered or aromatic carboxylic acids occurs in the presence of the fluoroalkyldistannoxane [{Cl(C6F13CH2 CH2)2SnOSn(CH2CH2 -C6F13)2Cl}2] (1). The reaction gives 100% yield with a strict 1:1 ratio of the carboxylic acid and alcohol reactants, and the catalyst can be recycled without any loss of activity.

A practical and green chemical process: Fluoroalkyldistannoxane-catalyzed biphasic transesterification

There is no need for the recovery of the catalyst in the fluorous biphasic transesterification catalyzed by [{Cl(C6F13CH2CH2)2 SnOSn(C6F13CH2CH2) 2Cl}2] (1; see scheme), which results in quantitative conversions and yields. An FC-72 solution of the dimeric flouroalkyldistannoxane 1 can be recycled repeatedly without having to recover the neat catalyst.