280743-82-0

Basic information

• Product Name: NC₅H₄(CH₂)2OP(C₆H₅)2
• CAS NO: 280743-82-0
• Molecular Weight: 307.332
• Mol File: 280743-82-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: NC₅H₄(CH₂)2OP(C₆H₅)2(CAS DataBase Reference)
• NIST Chemistry Reference: NC₅H₄(CH₂)2OP(C₆H₅)2(280743-82-0)
• EPA Substance Registry System: NC₅H₄(CH₂)2OP(C₆H₅)2(280743-82-0)

Safety Data

• Hazardous Substances Data: 280743-82-0(Hazardous Substances Data)

Upstream product

• 103-74-2 2-(2-Hydroxyethyl)pyridine 
• 1079-66-9 chloro-diphenylphosphine 

Downstream Products

• 282717-73-1 [Pd(C₄H₇){o-C₅H₄N(CH₂)2OPPh₂}][O₃SCF₃] 
• 282717-79-7 ((C₉H₉)PdNC₅H₄(CH₂)2OP(C₆H₅)2)⁽¹⁺⁾*CF₃SO₃^(1-)=((C₉H₉)PdNC₅H₄(CH₂)2OP(C₆H₅)2)(CF₃SO₃) 

Relevant articles and documents

Bite angle effect of bidentate P-N ligands in palladium catalysed allylic alkylationf

Two series of new bidentate P-N ligands have been synthesized. Application of these ligands in the palladium catalysed allylic alkylation of crotyl chloride and cinnamyl chloride leads to the preferential formation of the branched product. A larger bite angle of the ligand leads to higher regioselectivity. Stoichiometric alkylation of the complex [Pd(C4H7){p-MeOC6H4C=N(CH 2)4OPPh2}][O3SCF3] proceeds with 88% regioselectivity to the branched product. The Royal Society of Chemistry 2000.