28286-77-3

Basic information

• Product Name: diethyl 2-benzoyl-2-methylmalonate
• Synonyms: diethyl 2-benzoyl-2-methylmalonate
• CAS NO: 28286-77-3
• Molecular Weight: 278.305
• Mol File: 28286-77-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: diethyl 2-benzoyl-2-methylmalonate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl 2-benzoyl-2-methylmalonate(28286-77-3)
• EPA Substance Registry System: diethyl 2-benzoyl-2-methylmalonate(28286-77-3)

Safety Data

• Hazardous Substances Data: 28286-77-3(Hazardous Substances Data)

Upstream product

• 201230-82-2 carbon monoxide 
• 609-08-5 Diethyl methylmalonate 
• 98-80-6 phenylboronic acid 
• 3277-27-8 diethyl benzoylphosphonate 
• 108-86-1 bromobenzene 

Downstream Products

• 65-85-0 benzoic acid 
• 609-08-5 Diethyl methylmalonate 
• 532-96-7 N-benzoyl-N'-phenylhydrazine 

Relevant articles and documents

Pd-catalyzed carbonylation for the construction of tertiary and quaternary carbon centers with sp3 carbon partners

The first examples of a Pd-catalyzed carbonylation of aryl boronic acids with sp3 carbon partners are presented. Various boronic acids were shown to react with 1,3-diesters and 1,3-diketones to afford structurally unique carbonyl compounds. By

ACYLATION OF ACTIVE METHYLENE COMPOUNDS VIA PALLADIUM COMPLEX-CATALYZED CARBONYLATIVE CROSS-COUPLING OF ORGANIC HALIDES

New procedures for acylation of active methylene compounds via palladium complex-catalyzed carbonylation of organic halides are disclosed.