2832-45-3 Usage
Description
Sodium 1-hexanesulfonate, also known as 1-hexanesulfonic acid sodium salt, is an organic compound with the chemical formula C6H13SO3Na. It is a white crystalline solid that is soluble in water and exhibits ionic properties. Sodium 1-hexanesulfonate is commonly used in various chemical and analytical applications due to its unique characteristics.
Uses
Used in Organic Chemistry:
Sodium 1-hexanesulfonate is used as a base in organic coupling reactions, such as the Suzuki coupling reactions. It facilitates the formation of carbon-carbon bonds, which are essential in the synthesis of various organic compounds.
Used in High-Performance Liquid Chromatography (HPLC):
Sodium 1-hexanesulfonate is used as an ion pairing reagent in HPLC. It helps in the separation and analysis of peptides and proteins by improving their solubility and peak shape in the chromatographic process.
Used in Capillary Electrophoresis:
In high-performance capillary electrophoresis, Sodium 1-hexanesulfonate is employed for the analysis of peptides. It aids in the separation of these biomolecules based on their size and charge, providing accurate and efficient results.
General Description:
Sodium 1-hexanesulfonate is available as a concentrate for 6x1 L ready-to-use solutions. To prepare a 0.005 M eluent solution, dilute the contents of one ampule (~0.3 M) with HPLC grade water up to 1 L. This solution can be used in various analytical techniques, such as HPLC and capillary electrophoresis, for the separation and analysis of peptides and proteins.
Check Digit Verification of cas no
The CAS Registry Mumber 2832-45-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,8,3 and 2 respectively; the second part has 2 digits, 4 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 2832-45:
(6*2)+(5*8)+(4*3)+(3*2)+(2*4)+(1*5)=83
83 % 10 = 3
So 2832-45-3 is a valid CAS Registry Number.
InChI:InChI=1/C6H14O3S.Na/c1-2-3-4-5-6-10(7,8)9;/h2-6H2,1H3,(H,7,8,9);/q;+1/p-1/rC6H13NaO3S/c1-2-3-4-5-6-11(8,9)10-7/h2-6H2,1H3
2832-45-3Relevant articles and documents
N-Sulfonyl homoserine lactones as antagonists of bacterial quorum sensing
Castang, Sandra,Chantegrel, Bernard,Deshayes, Christian,Dolmazon, René,Gouet, Patrice,Haser, Richard,Reverchon, Sylvie,Nasser, William,Hugouvieux-Cotte-Pattat, Nicole,Doutheau, Alain
, p. 5145 - 5149 (2007/10/03)
A series of 11 N-sulfonyl homoserine lactones has been synthesised. Some of them were found to competitively inhibit the action of 3-oxohexanoyl-L- homoserine lactone, the natural inducer of bioluminescence in the bacterium Vibrio fischeri. Molecular modeling suggests a possible explanation based on the prevention of structural rearrangements necessary for the formation of the active dimer of LuxR.
One-Step Synthesis of Esters of Aliphatic β-Chloro Sulfonic Acids. Their Sequential Conversion to Other Sulfonic Acid Derivatives
Heller, Morgan S.,Lorah, Dennis P.,Cox, Charles G.
, p. 134 - 137 (2007/10/02)
A one-step synthesis of methyl 2-chlorohexane-1- and 2-chlorooctane-1-sulfonate by the novel free-radical addition of methyl chlorosulfonate to 1-hexene and 1-octene, respectively, is reported.These products were converted by standard techniques into the corresponding sodium and benzylthiuronium β-chlorosulfonic acid salts and sulfonyl chlorides.Dehydrochlorination of these latter products with triethylamine affored regiospecific formation of trans-α,β-unsaturated sulfonyl chlorides, which were transformed by conventional methods into sodium and benzylthiuroniumunsaturated and saturated sulfonic acid salts.Eleven new compositions of matter are reported.
