2863-45-8Relevant articles and documents
Electron transfer in the peroxytrifluoroacetic acid-assisted sulfoxidation and oxidative destruction of benzhydryl sulfides
Akopova,Morkovnik,Khrustalev,Bicherov
, p. 1164 - 1175 (2014/03/21)
The reactions of benzhydryl sulfides Ph2CHSCH2R (R = H, CONH2, COOH, CN) with peroxytrifluoroacetic acid in CF 3COOH were studied experimentally and by the quantum chemical density functional theory (DFT) method and exhibited an unusual dependence on the substituent R. When R≠H, a complicated oxidative destruction of the substrates occurs to form 2,4,6-tribenzhydrylphenol as one of the products, while in the case of R = H, the starting benzhydryl sulfide is smoothly sulfoxidated. This fact is due to the common electron transfer from the substrate to reagent at the initial step and the difference in subsequent transformations of the species formed.
Reaction of Thiobenzophenone S-Oxide (Diphenylsulfine) with Carbon Nucleophiles
Ohno, Atsuyoshi,Uohama, Misao,Oka, Shinzaburo
, p. 3231 - 3232 (2007/10/02)
The reaction of diphenylsulfine with a Grignard reagent or alkyllithium gives a variety of products depending on the structure of the Grignard reagent or alkyllithium.
