28691-27-2Relevant articles and documents
Tandem catalytic acrylonitrile cross-metathesis and hydrogenation of nitriles with ruthenium catalysts: Direct access to linear α,ω- aminoesters from renewables
Miao, Xiaowei,Fischmeister, Cédric,Bruneau, Christian,Dixneuf, Pierre H.,Dubois, Jean-Luc,Couturier, Jean-Luc
scheme or table, p. 1410 - 1414 (2012/10/08)
Fraternité, Solidarité & complémentarité en Catalyse: Tandem alkene cross-metathesis of acrylonitrile with long-chain alkene and hydrogenation catalysis is performed by using a single ruthenium-alkylidene catalyst precursor. The protocol allows the catalytic transformation of unsaturated fatty acids, derivatives of plant oils, into α,ω-aminoesters. A key step involves the reduction of nitrile-ester intermediates into aminoesters, the precursors of polyamides, with alkene metathesis catalyst residue under mild conditions. Copyright