288570-39-8

Basic information

• Product Name: (2-benzoylphenyl)(4-methoxyphenyl)methanone
• Synonyms: (2-benzoylphenyl)(4-methoxyphenyl)methanone
• CAS NO: 288570-39-8
• Molecular Weight: 316.356
• Mol File: 288570-39-8.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: (2-benzoylphenyl)(4-methoxyphenyl)methanone(CAS DataBase Reference)
• NIST Chemistry Reference: (2-benzoylphenyl)(4-methoxyphenyl)methanone(288570-39-8)
• EPA Substance Registry System: (2-benzoylphenyl)(4-methoxyphenyl)methanone(288570-39-8)

Safety Data

• Hazardous Substances Data: 288570-39-8(Hazardous Substances Data)

Upstream product

• 1151-15-1 2-(4-methoxybenzoyl)benzoic acid 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 5398-11-8 3-phenylphthalide 
• 3586-83-2 1-(4-methoxy-phenyl)-3-phenyl-isobenzofuran 
• 112219-63-3 (4-methoxyphenyl)magnesium iodide 
• 612-35-1 2-Benzylbenzoic acid 
• 56153-61-8 2-benzyl-benzonitrile 
• 98-88-4 benzoyl chloride 
• 100-07-2 4-methoxy-benzoyl chloride 
• 7702-22-9 2-benzyl-4'-methoxy-benzophenone 
• 7697-37-2 nitric acid 
• 7664-93-9 sulfuric acid 
• 41140-80-1 acide (methoxy-4' diphenylmethyl)-2 benzoique 
• 71-43-2 benzene 

Downstream Products

• 1401613-67-9 C₃₁H₃₆O₅ 
• 23674-15-9 9-(p-methoxyphenyl)anthracene 

Relevant articles and documents

Oxidative cleavage of 1,3-diaryl/(heteroaryl)benzo[c]furans into 1,2-diaroyl/(heteroaroyl)benzenes using selenium dioxide

Reaction of 1,3-disubstituted isobenzofurans (IBFs) with selenium dioxide in tetrahydrofuran (THF) at room temperature led to the formation of 1,2-diaroyl/(heteroaroyl)benzenes in good to excellent yields.

Synthesis of annulated arenes and heteroarenes involving lewis acid-mediated regioselective annulation of unsymmetrical 1,2-(Diaryl/ diheteroarylmethine)dipivalates

A ZnBr2-mediated regioselective annulation of unsymmetrical 1,2-diarylmethinedipivalates in DCM at room temperature led to the formation of annulated arenes and heteroarenes. The annulation of the dipivalate proceeds through the intermediacy of

Copper-catalyzed benzylic C-H oxygenation under an oxygen atmosphere via N-H imines as an intramolecular directing group

Copper-catalyzed benzylic C-H oxygenation under an oxygen atmosphere was developed starting from carbonitriles and Grignard reagents via N-H imine intermediates. The present process is characterized by the following two-step sequence in a one-pot manner: (1) addition of Grignard reagents to carbonitriles to form N-H imines and (2) benzylic C-H oxygenation (C=O bond formation) triggered by 1,5-hydrogen atom transfer with transient iminyl copper species.