2895-07-0Relevant articles and documents
1,1,1,3,3,5,5-heptamethyltrisiloxane preparation method
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Paragraph 0015; 0016, (2016/11/21)
The present invention discloses a 1,1,1,3,3,5,5-heptamethyltrisiloxane preparation method, wherein 1,1,1,3,3,3-hexamethyldisiloxane and 1,1,3,3-tetramethyldisiloxane are subjected to co-hydrolysis for 1-4 h under catalysis of concentrated sulfuric acid to obtain 1,1,1,3,3-pentamethyldisiloxane, the 1,1,1,3,3-pentamethyldisiloxane and dimethyl dimethoxy silicane are subjected to co-hydrolysis for 1-3 h under catalysis of concentrated sulfuric acid, rectification is performed, and the distillate at a temperature of 135 DEG C is collected so as to obtain the 1,1,1,3,3,5,5-heptamethyltrisiloxane product. According to the present invention, the method has characteristics of strong target property, less by-product content in the product, and easy separation.
METAL COMPLEX-CATALYZED REDISTRIBUTION REACTIONS OF ORGANOSILANES. IV. REDISTRIBUTION REACTIONS OF METHYLSILOXANES CATALYZED BY TRANSITION METAL COMPLEXES
Gustavson, Wayne A.,Epstein, Paul S.,Curtis, M.D.
, p. 87 - 98 (2007/10/02)
Redistribution reactions of a variety of hydrogen-substituted siloxanes are catalyzed by various transition metal complexes of iridium and rhodium.The products arise from breaking and remaking of Si-C, Si-H, and Si-O bonds.Siloxanes not possessing a Si-H bond are inert under the conditions studied.The most favored reaction pathway appears to scramble preferentially the groups directly attached to the silicon bearing the hydrogen atom.A new cyclo-iridiadisiloxane, (L = Ph3P; R = Me3SiO) is reported.This compound exists in three isomeric forms as a consequence of the spatial arrangements of the R and Me groups on the ring.