290349-97-2

Basic information

• Product Name: [Rh(BisP*)(deuteriomethanol)2]BF₄
• CAS NO: 290349-97-2
• Molecular Weight: 496.033
• Mol File: 290349-97-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [Rh(BisP*)(deuteriomethanol)2]BF₄(CAS DataBase Reference)
• NIST Chemistry Reference: [Rh(BisP*)(deuteriomethanol)2]BF₄(290349-97-2)
• EPA Substance Registry System: [Rh(BisP*)(deuteriomethanol)2]BF₄(290349-97-2)

Safety Data

• Hazardous Substances Data: 290349-97-2(Hazardous Substances Data)

Upstream product

• 290356-61-5 [Rh((S,S)-1,2-bis(tert-butylmethylphosphino)ethane)(HPhC₂(CO₂Me)NHCOMe)]BF₄ 
• 1333-74-0 hydrogen 
• 811-98-3 d⁽⁴⁾-methanol 
• 52386-78-4 N-acetyl dehydrophenylalanine methyl ester 

Downstream Products

• 290356-61-5 [Rh((S,S)-1,2-bis(tert-butylmethylphosphino)ethane)(HPhC₂(CO₂Me)NHCOMe)]BF₄ 
• 349537-83-3 [((CH₃)3C(CH₃)PCH₂CH₂P(CH₃)C(CH₃)3)Rh(CH₂C(C₆H₄Cl)NHCOCH₃)]⁽¹⁺⁾ 
• 307498-81-3 [((CH₃)3C(CH₃)PCH₂CH₂P(CH₃)C(CH₃)3)Rh(CH₂C(C₆H₅)NHCOCH₃)]⁽¹⁺⁾ 
• 307498-81-3 [((CH₃)3C(CH₃)PCH₂CH₂P(CH₃)C(CH₃)3)Rh(CH₂C(C₆H₅)NHCOCH₃)]⁽¹⁺⁾ 

Relevant articles and documents

Trinuclear rhodium hydride complexes

Three novel trinuclear rhodium hydride complexes of the type {[Rh(PP*)H]3(μ2-H)3(μ3- H)}[BF4]2 containing diphosphines Tangphos, t-Bu-BisP* and Me-DuPHOS have been synthesised. The new compounds are very stable. Their structures have been characterized by X-ray analysis in the solid state and by NMR-spectroscopic investigations in solution.