290356-69-3

Basic information

• Product Name: (3R,4S,R_S)-4-(hydroxymethyl)-1-[(1S)-isoborneol-10-sulfinyl]-3-methoxycyclohexene
• Synonyms: (3R,4S,R_S)-4-(hydroxymethyl)-1-[(1S)-isoborneol-10-sulfinyl]-3-methoxycyclohexene
• CAS NO: 290356-69-3
• Molecular Weight: 342.5
• Mol File: 290356-69-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3R,4S,R_S)-4-(hydroxymethyl)-1-[(1S)-isoborneol-10-sulfinyl]-3-methoxycyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: (3R,4S,R_S)-4-(hydroxymethyl)-1-[(1S)-isoborneol-10-sulfinyl]-3-methoxycyclohexene(290356-69-3)
• EPA Substance Registry System: (3R,4S,R_S)-4-(hydroxymethyl)-1-[(1S)-isoborneol-10-sulfinyl]-3-methoxycyclohexene(290356-69-3)

Safety Data

• Hazardous Substances Data: 290356-69-3(Hazardous Substances Data)

Upstream product

• 153782-87-7 (3R,4R,R_S)-1-[(1S)-isoborneol-10-sulfinyl]-3-methoxy-4-methoxycarbonylcyclohexene 

Downstream Products

• 192460-94-9 (4R)-4-(hydroxymethyl)-cyclohex-2-ene-1-one 
• 116195-09-6 bis-{(1S,2R,4R)-2-hydroxy-7,7-dimethylbicyclo[2.2.1]hept-1-ylmethyl}disulfide 

Relevant articles and documents

An investigation of the behaviour of α,β-unsaturated sulfoxides in the presence of trimethylsilyl iodide

A mild, efficient and seemingly general method for converting α,β-unsaturated sulfoxides into carbonyl compounds by means of trimethylsilyl iodide (TMSI) is described. Experiments on different substrates and trimethylsilyl halides lead to the conclusion that the oxidation state of the sulfur atom, on one hand, and halogen kind in TMSX on the other, assume a determining role in the progression of the reaction. The ease of experimental procedure, the possibility of 1H NMR monitoring, and good yields of final products constitute advantages of the TMSI-promoted conversion of α,β-unsaturated sulfoxides into carbonyl compounds.