29046-78-4

Basic information

• Product Name: NICKEL CHLORIDE, DIMETHOXYETHANE ADDUCT
• Synonyms: NICKEL(II) CHLORIDE DIMETHOXYETHANE ADDUCT;NICKEL CHLORIDE, DIMETHOXYETHANE ADDUCT;Nickel(II) chloride ethylene glycol dimethyl ether complex;NiCl2 glyme;Nickel(II) chloride, dimethoxyethane adduct, min. 97%;Nickel(II) chloride ethylene glycol diMethyl ether coMplex 98%;Dichloro(dimethoxyethane)nickel;Dichloro(1,2-dimethoxyethane)nickel
• CAS NO: 29046-78-4
• Molecular Formula: C₄H₁₀Cl₂NiO₂
• Molecular Weight: 219.72
• Product Categories: metal halide
• Mol File: 29046-78-4.mol
• Article Data: 4

Chemical Properties

• Melting Point: >300 °C
• Appearance: yellow/Powder
• Storage Temp.: Inert atmosphere,Room Temperature
• Relative Polarity: 0.231
• Sensitive: moisture sensitive
• CAS DataBase Reference: NICKEL CHLORIDE, DIMETHOXYETHANE ADDUCT(CAS DataBase Reference)
• NIST Chemistry Reference: NICKEL CHLORIDE, DIMETHOXYETHANE ADDUCT(29046-78-4)
• EPA Substance Registry System: NICKEL CHLORIDE, DIMETHOXYETHANE ADDUCT(29046-78-4)

Safety Data

• Hazard Codes: T,N
• Statements: 23/24/25-36/37/38-42/43-45-50/53-43-36/38-25
• Safety Statements: 26-36/37/39-61-60-45-36/37-53
• RIDADR: 3288
• WGK Germany: 3
• Hazardous Substances Data: 29046-78-4(Hazardous Substances Data)

Usage

Uses

Different sources of media describe the Uses of 29046-78-4 differently. You can refer to the following data:
1. Nickel(II) chloride ethylene glycol dimethyl ether is commonly used as a catalyst for the synthesis of various organic compounds.
2. Nickel(II) chloride ethylene glycol dimethyl ether complex can be used:As a catalyst for the borylation of racemic benzylic chloride to synthesize enantioenriched benzylic boronic esters.As a promoter for the trifluoromethylation of alkyl iodides to synthesize broad range of alkyl-CF3 compounds.For the synthesis of nickel bis(benzimidazol-2-ylidene) pincer complexes which can be used for electrocatalytic reduction of CO2 to CO.As a Lewis acid catalyst for C-acylation β-ketoesters through photoactivation by visible light.

Upstream product

• 110-71-4 1,2-dimethoxyethane 
• 83864-14-6 nickel dichloride 
• 122-51-0 orthoformic acid triethyl ester 

Downstream Products

• 354810-32-5 (t-Bu₃PN₃CH₂SPh)2NiCl₂ 
• 227933-80-4 ((C₆H₁₁)2PCH₂CH(CH₃)SCH₂C₆(CH₃)5)NiCl₂ 
• 346447-05-0 bis(η5-1-menthyl-4,7-dimethylindenyl)nickel(II) 
• 1005390-62-4 [Ni(2-methyloxy(diphenylphosphino)pyridine)Cl₂] 
• 1035559-69-3 NiCl₂(N(o-iPrOC₆H₄)(C(SiMe₃)(CH₂C₅H₄N-2)) 
• 1035559-64-8 Ni[N(o-PhCH₂OC₆H₄)(C(SiMe₃)(CHC₅H₄N-2)]2 
• 1033772-47-2 [((Me)NN₂)NiCl] 
• 1038986-83-2 [Ni(bis(2-picolyloxy)phenylphosphine)Cl₂] 
• 1005390-59-9 2-[(diphenylphosphino)methyl]pyridinenickel dichloride 
• 1111259-68-7 2-[3-(diphenylphosphino)propyl]pyridinenickel dichloride 
• 1111259-70-1 2-(2-(diphenylphosphino)phenyl)pyridinenickel dichloride 
• 15685-41-3 [2-(2-(diphenylphosphino)ethyl)pyridine]nickel(II) chloride 
• 1130640-79-7 [NiCl₂(2-((diphenylphosphinooxy)methyl)-4,4-dimethyl-4,5-dihydrooxazole)] 
• 1157858-98-4 2-[2-(di-2-tolylphosphino)ethyl]pyridinenickel dichloride 

Relevant articles and documents

Nickel(II) complexes with imino-imidazole chelating ligands bearing pendant donor groups (SR, OR, NR2, PR2) as precatalysts in ethylene oligomerization

New imino-imidazole ligands bearing a pendant donor function L were synthesized in excellent yields. The corresponding nickel(II) complexes [NiCl2(imino-imidazole-L)]n (L = (CH2) 2SMe (2a), (CH2)2OMe (2b), (CH 2)2NEt2 (2c), (CH2) 2PPh2 (2d), (C6H4)-p-OMe (2e), (CH2)3OMe (2f), (CH2)3CH3 (2g); n = 1, 2) were prepared and characterized by FT-IR spectroscopy and elemental analysis. Furthermore, the coordination geometry around the metal center in the dinuclear complex 2a and the mononuclear complexes 2c and 2e was unambiguously established by single crystal X-ray diffraction. All complexes have been evaluated for the oligomerization of ethylene in the presence of EtAlCl2 or MAO (methylaluminoxane) as cocatalyst, and mostly dimers and trimers were produced. Better activities were observed with EtAlCl 2 as cocatalyst than with MAO.

Method for the production of nickel(0)-phosphorous ligand complexes

The present invention provides a process for preparing nickel(0)-phosphorus ligand complexes starting from nickel(II)-ether adducts.