29074-04-2

Basic information

• Product Name: T-BUTYL D-GLUCOSIDE
• Synonyms: T-BUTYL D-GLUCOSIDE;tert-Butylb-D-glucopyranoside;T-BUTYL GLUCOSIDE;1-O-tertbutylbeta-D-glucopyranose
• CAS NO: 29074-04-2
• Molecular Formula: C10H20O6
• Molecular Weight: 236.2622
• Mol File: 29074-04-2.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: T-BUTYL D-GLUCOSIDE(CAS DataBase Reference)
• NIST Chemistry Reference: T-BUTYL D-GLUCOSIDE(29074-04-2)
• EPA Substance Registry System: T-BUTYL D-GLUCOSIDE(29074-04-2)

Safety Data

• Hazardous Substances Data: 29074-04-2(Hazardous Substances Data)

Upstream product

• 2297-41-8 pyridin-2-yl 1-thio-β-D-glucopyranoside 
• 75-65-0 tert-butyl alcohol 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 
• 74352-37-7 (2R,3R,4S,5R,6S)-2-(acetoxymethyl)-6-(pyridin-2-ylthio)tetrahydro-2H-pyran-3,4,5-triyl triacetate 
• 13035-51-3 tert-butyl-(tetra-O-acetyl-β-D-glucopyranoside) 

Downstream Products

• 50-99-7 D-glucose 
• 6564-72-3 2,3,4,6-tetra-O-benzyl-D-glucopyranose 
• 59531-24-7 2,3,4,6-tetra-O-benzyl-D-glucopyranoside 
• 67525-69-3 (3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-2-((benzyloxy)methyl)-6-(tert-butoxy)tetrahydro-2H-pyran 

Relevant articles and documents

The tertiary-butyl group: Selective protection of the anomeric centre and evaluation of its orthogonal cleavage

The tertiary-butyl group has not been examined extensively as a protecting group. In this work, we describe the synthesis of tert-butyl glycosides via the Fischer glycosylation protocol. Furthermore, its utility as a temporary anomeric protecting group was evaluated. A range of differentially protected monosaccharides was used to investigate the stability of the tert-butyl group upon the introduction of other protecting groups; and compatibility of its cleavage in the presence of the latter.

Chemistry of the glycoside linkage. Exceptionally fast efficient formation of glycosides by remote activation

-