29086-12-2

Basic information

• Product Name: Methanamine, N-(phenylmethylene)-, (Z)-
• CAS NO: 29086-12-2
• Molecular Formula: C8H9N
• Molecular Weight: 119.166
• Mol File: 29086-12-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Methanamine, N-(phenylmethylene)-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanamine, N-(phenylmethylene)-, (Z)-(29086-12-2)
• EPA Substance Registry System: Methanamine, N-(phenylmethylene)-, (Z)-(29086-12-2)

Safety Data

• Hazardous Substances Data: 29086-12-2(Hazardous Substances Data)

Upstream product

• 119-61-9 benzophenone 
• 80055-49-8 (E)-benzaldehyde O-acetyl oxime 
• 103-67-3 benzyl-methyl-amine 

Downstream Products

• 762289-15-6 tert-butyl (3S,7R,Z)-1-methyl-2-oxo-7-phenyl-2,3,4,7-tetrahydro-1H-azepin-3-ylcarbamate 
• 762289-11-2 tert-butyl (2S)-1-(methyl(1-phenylallyl)amino)-1-oxopent-4-en-2-ylcarbamate 
• 762289-17-8 (3S,7R,Z)-3-amino-1-methyl-7-phenyl-3,4-dihydro-1H-azepin-2(7H)-one 
• 132815-77-1 (3R^*,4R^*)-2,4-dimethyl-3-phenyl-1,2-thiazetidine 1,1-dioxide 
• 132815-77-1 (3R^*,4S^*)-2,4-dimethyl-3-phenyl-1,2-thiazetidine 1,1-dioxide 
• 6601-37-2 N-methyl-ethanesulfonamide 
• 55881-64-6 (+/-)cis-2-methyl-3,4-diphenyl-1,2-thiazetidine 1,1-dioxide 
• 55881-64-6 2-methyl-3r,4t-diphenyl-[1,2]thiazetidine 1,1-dioxide 
• 86766-70-3 N-methyl-N-<α-phenyl-allyl>amine 
• 119011-70-0 (1R,4R,5S)-6-Dimethylamino-3-methyl-1,4,5-triphenyl-3-aza-bicyclo[3.1.0]hexan-2-one 
• 119011-70-0 (1R,4S,5S)-6-Dimethylamino-3-methyl-1,4,5-triphenyl-3-aza-bicyclo[3.1.0]hexan-2-one 
• 119011-76-6 (1R,4R,5S)-6-Dimethylamino-3-methyl-4,5-diphenyl-1-trimethylsilanyl-3-aza-bicyclo[3.1.0]hexan-2-one 

Relevant articles and documents

Initiators based on benzaldoximes: Bimolecular and covalently bound systems

Typical bimolecular photoinitiators (PIs) for radical polymerization of acrylates show only poor photoreactivity because of the undesired effect of back electron transfer. To overcome this limitation, PIs consisting of a benzaldoxime ester and various sensitizers based on aromatic ketones were introduced. The core of the photoinduced reactivity was established by laser flash photolysis, photo-CIDNP, and EPR experiments at short time scales. According to these results, the primarily formed iminyl radicals are not particularly active. The polymerization is predominantly initiated by C-centered radicals. Photo-DSC experiments show reactivities comparable to that of classical monomolecular type I PIs like Darocur 1173.