29369-71-9

Basic information

• Product Name: Benzenamine, N-3-butenyl-
• CAS NO: 29369-71-9
• Molecular Formula: C10H13N
• Molecular Weight: 147.22
• Mol File: 29369-71-9.mol
• Article Data: 18

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-3-butenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-3-butenyl-(29369-71-9)
• EPA Substance Registry System: Benzenamine, N-3-butenyl-(29369-71-9)

Safety Data

• Hazardous Substances Data: 29369-71-9(Hazardous Substances Data)

Upstream product

• 131196-24-2 2-phenyl-3,6-dihydro-2H-[1,2]thiazine 1-oxide 
• 62-53-3 aniline 
• 24850-33-7 allyltributylstanane 
• 103-70-8 Formanilid 
• 103-71-9 phenyl isocyanate 
• 106-95-6 allyl bromide 
• 778-29-0 but-3-enyl 4-methylbenzenesulfonate 
• 1172142-57-2 N-(but-3-enyl)-N-phenyl-2-nitrobenzenesulfonamide 
• 222851-56-1 N-phenylsulfinylamine 
• 1746-13-0 allyl phenyl ether 
• 100-61-8 N-methylaniline 
• 283594-49-0 4-(N-phenylamino)-1-butyl acetate 
• 62001-29-0 N-phenyl-1H-benzotriazolyl-1-methanamine 
• 346713-20-0 allylsamarium bromide 

Downstream Products

• 135523-36-3 (E)-N-(3-butenyl)-N-(4-methoxy-2-methyl-1-methylene-2-butenyl)aniline 
• 87205-06-9 N-(3-butenyl)-4-methyl-N-phenyloxazole-5-carboxamide 
• 87205-07-0 N-(3-butenyl)-2,4-dimethyl-N-phenyloxazole-5-carboxamide 
• 667466-00-4 N-(trifluoromethylsulfonyl)-N-phenylaminobut-3-ene 
• 38369-76-5 1-phenyl-1-aza-2-bora cyclohexane 
• 1172142-69-6 methyl 2-[N-(but-3-enyl)-N-phenylsulfamoyl]acetate 
• 1152500-15-6 C₁₇H₁₉N 
• 13424-22-1 4-(N-methyl-N-phenylamino)-1-butene 
• 837-56-9 1-phenyl-2-phenylpyrrole 
• 117896-68-1 1-phenyl-4-chloropiperidine 
• 56235-33-7 1-phenyl-5,6-dihydropyridin-2(1H)-one 
• 1416437-62-1 1,2-diphenyl-4-vinyl-4,5-dihydro-1H-imidazole 
• 1403587-49-4 C₁₄H₁₅NO 
• 1418218-15-1 N-(but-3-enyl)-N-phenylacrylamide 

Relevant articles and documents

Nickel-Catalyzed Aminofluoroalkylation of Alkenes: Access to Difluoroalkylated N-Containing Heterocyclic Compounds

A nickel-catalyzed aminofluoroalkylative cyclization of unactive alkenes with iododifluoromethyl ketones was developed to construct versatile difluoroalkylated Nitrogen-containing heterocycles including aziridines, pyrrolidines and piperidines in moderate to high yields. This method features a broad substrate scope and has been demonstrated on gram scale.

A 5 + 1 Protic Acid Assisted Aza-Pummerer Approach for Synthesis of 4-Chloropiperidines from Homoallylic Amines

We report that HCl·DMPU induces the formation of (thiomethyl)methyl carbenium ion from DMSO under mild conditions. Homoallylic amines react with this electrophile to generate 4-chloropiperidines in good yields. The method applies to both aromatic and aliphatic amines. The use of HCl·DMPU as both non-nucleophilic base and chloride source constitutes an environmentally benign alternative for piperidine formation. The reaction has a broad substrate scope, and the conditions offer good chemical yields with high functional group tolerance and scalability.

Chemoselective Schwartz Reagent Mediated Reduction of Isocyanates to Formamides

Addition of the in situ generated Schwartz reagent to widely available isocyanates constitutes a chemoselective, high-yielding, and versatile approach to the synthesis of variously functionalized formamides. Steric and electronic factors or the presence of sensitive functionalities (esters, nitro groups, nitriles, alkenes) do not compromise the potential of the method. Full preservation of the stereochemical information contained in the starting materials is observed. The use of formamides in the nucleophilic addition of organometallic reagents (Chida-Sato allylation, Charette-Huang addition to imidoyl triflate activated amides, Matteson homologation of boronic esters) is briefly investigated.