2941-55-1

Basic information

• Product Name: ETHIOLATE
• Synonyms: ACITHION;5-ETHYL DIETHYLTHIOCARBAMATE;ETHIO;ETHIOLAT;ETHIOLATE;ETHOSAN;DHANUMIT;DEVIASTRA
• CAS NO: 2941-55-1
• Molecular Formula: C₆H₉Cl₂NOS
• Molecular Weight: 161.27
• Mol File: 2941-55-1.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 215.6 °C at 760 mmHg
• Flash Point: 84.2 °C
• Appearance: /
• Density: 0.99 g/mL at 20 °C
• Vapor Pressure: 0.146mmHg at 25°C
• Refractive Index: 1.6370 (estimate)
• Storage Temp.: APPROX 4°C
• PKA: -1.22±0.70(Predicted)
• BRN: 1755151
• CAS DataBase Reference: ETHIOLATE(CAS DataBase Reference)
• NIST Chemistry Reference: ETHIOLATE(2941-55-1)
• EPA Substance Registry System: ETHIOLATE(2941-55-1)

Safety Data

• Hazard Codes: Xn
• Statements: 22
• RIDADR: 2902
• WGK Germany: 3
• RTECS: EZ7290000
• HazardClass: 6.1(b)
• PackingGroup: III
• Hazardous Substances Data: 2941-55-1(Hazardous Substances Data)

Usage

Description

ETHIOLATE, also known as S-ethyl Ester N,N-Diethyl-carbamothioic Acid, is a chemical compound that functions as a herbicide and pesticide. It is commonly found in avocados and has been utilized in agricultural applications to control the growth of unwanted plants and protect crops.

Uses

Used in Agriculture:
ETHIOLATE is used as a herbicide for controlling the growth of unwanted plants in agricultural fields. It helps to protect crops from potential damage caused by weeds and other invasive plant species.
Used in Pest Control:
In addition to its herbicidal properties, ETHIOLATE also serves as a pesticide, helping to eliminate pests that can harm crops and reduce their yield. This dual functionality makes it a valuable tool in maintaining the health and productivity of agricultural lands.
Used in Avocado Production:
Since ETHIOLATE is found in avocados, it may have potential applications in the avocado industry, such as enhancing the growth and protection of avocado trees from pests and weeds. However, further research would be needed to explore the specific benefits and optimal usage of ETHIOLATE in this context.

InChI:InChI=1/C7H15NOS/c1-4-8(5-2)7(9)10-6-3/h4-6H2,1-3H3

Upstream product

• 88-10-8 N,N-diethylcarbamyl chloride 
• 811-51-8 sodium thioethylate 
• 75-03-6 ethyl iodide 
• 109-89-7 diethylamine 
• 140-90-9 sodium O-ethyl dithiocarbonate 
• 26292-53-5 diethylammonium hydrogen sulphate 
• 22318-01-0 diethylamonium N,N'-dimethylmonothiocarbamate 
• 75-00-3 chloroethane 
• 21055-93-6 sodium salt of diethylthiocarbamic acid 
• 201230-82-2 carbon monoxide 
• 74-96-4 ethyl bromide 
• 16868-29-4 S-vinyl N,N-diethylthiolcarbamate 

Downstream Products

• 75-04-7 ethylamine 

Relevant articles and documents

New facile one-pot synthesis of S-alkyl thiolcarbamates from xanthogenate in water

A simple and efficient one-pot synthesis was developed for the preparation of S-alkyl thiolcarbamates from xanthogenate without catalyst using water as a solvent. The water can be recycled after removal of the product. The significant features of this protocol are: operational simplicity, mild reaction conditions, recycling of solvent and high product yields. Starting basic alkyl xanthogenate reacts with alkyl ammonium sulfate (aryl ammonium sulfate) and hydrogen peroxide (molar ratio 1:0.55:1) in water at 40 C for 1 h, followed by additional heating at 70-110 C for 1-2.3 h. Good to excellent yields were achieved using ammonium sulfate in 10 % molar excess. Graphical abstract: [Figure not available: see fulltext.]

Practical synthesis of S-alkyl thiocarbamate herbicides by carbonylation of amines with carbon monoxide and sulfur

An industrial and economic carbonylation of amines with carbon monoxide and sulfur has been developed for the synthesis of S-alkyl thiocarbamate herbicides. In the presence of potassium carbonate and solvent DMSO, S-alkyl thiocarbamates, such as thiobencarb and orbencarb (herbicides) are synthesized in excellent yields from amines, carbon monoxide, sulfur, and alkyl halides under mild conditions (1atm, 20°C).

REACTIONS OF UNSTABLE DIALKYLCARBAMOYL LITHIUMS WITH SULFUR COMPOUNDS

Unstable dialkylcarbamoyl lithiums, generated from the reaction of lithium dialkylamides with carbon monoxide, were successfully trapped by sulfur compounds (elemental sulfur, disulfides, carbon disulfide, and carbonyl sulfide) at low temperature, through their potent affinity with a sulfur atom.These efficient reactions were also applied to development of a facile synthetic method for thiocarbamates, useful herbicides, and thiooxamates.