2945-41-7Relevant articles and documents
General access to para-substituted styrenes
Langle, Sandrine,David-Quillot, Franck,Balland, Alexia,Abarbri, Mohamed,Duchêne, Alain
, p. 113 - 119 (2007/10/03)
A simple and efficient procedure has been developed for the synthesis of organogermanium compounds and styrenes para-substituted with groups containing an atom of the 14th group by one-pot reaction of halogenosilanes, germanes or stannanes, organic halides and magnesium using ultrasound methods.
Reactivities of triethylgermylborate in methanol
Nanjo, Masato,Matsudo, Kazuhiko,Mochida, Kunio
, p. 1086 - 1087 (2007/10/03)
The reactivity of lithium (triethylgermyl)triphenylborate, prepared from unsolvated triethylgermyllithium and triphenylborane, with organic substrates in methanol was investigated. The germylborates reacted with organic halides and acyl halides to give th
THE INFLUENCE OF THE MAGNETIC FIELD AS A TOOL FOR INVESTIGATION OF THE MECHANISM OF REACTIONS OF TRIETHYLGERMYL RADICALS
Taraban, M. B.,Leshina, T. V.,Salikhov, K. M.,Sagdeev, R. Z.,Molin, Yu. N.,et al.
, p. 31 - 36 (2007/10/02)
The influence of the external magnetic field on the product yield in the reaction of Et3GeM (where M = Na, K) with benzyl chloride was investigated.A mechanism for magnetic effects in this reaction is proposed.To verify the mechanism proposed, theoretical calculations of the recombination probability of triethylgermyl and benzyl singlet radical pairs were carried out.It is proposed that associated state of the organometallic compound in solution affects the cage and the magnetic effects.