29578-30-1

Basic information

• Product Name: cis-1-methyl-2-(1-methylethenyl)-cyclobutaneacetic acid
• CAS NO: 29578-30-1
• Molecular Weight: 168.236
• Mol File: 29578-30-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: cis-1-methyl-2-(1-methylethenyl)-cyclobutaneacetic acid(CAS DataBase Reference)
• NIST Chemistry Reference: cis-1-methyl-2-(1-methylethenyl)-cyclobutaneacetic acid(29578-30-1)
• EPA Substance Registry System: cis-1-methyl-2-(1-methylethenyl)-cyclobutaneacetic acid(29578-30-1)

Safety Data

• Hazardous Substances Data: 29578-30-1(Hazardous Substances Data)

Upstream product

• 28117-18-2 cis-(+/-)-2-acetyl-1-methylcyclobutaneacetic acid 
• 2344-80-1 Chloromethyltrimethylsilane 
• 412011-51-9 2-acetyl-1-methyl-1-cyclobutaneacetic acid 
• 74-95-3 1,1-dibromomethane 
• 19493-09-5 Methylenetriphenylphosphorane 
• 13404-66-5 6-methylbicyclo<4.2.0>octan-2-one 
• 53171-63-4 (+/-)-3-oximino-1,4,4-trimethylbicyclo<3.2.0>heptane 
• 53171-52-1 1,4,4-trimethyl-cis-bicyclo<3.2.0>heptan-2-one 
• 503-93-5 eucarvone 
• 28117-16-0 cis-6-methylbicyclo<4.2.0>oct-3-en-2-one 
• 73416-58-7 cis-(+/-)2,5-dimethylbicyclo<3.2.0>heptan-2-ol 
• 50459-35-3 (+/-)5-methylbicyclo<3.2.0>heptan-2-one 
• 116382-26-4 (+/-)2,5-dimethylhepta-1,6-dien-5-ol 
• 20962-70-3 ethyl 2-acetyl-4-methylpent-4-enoate 

Downstream Products

• 26532-22-9 grandisol 

Relevant articles and documents

STEREOSELECTIVE TOTAL SYNTHESIS OF RACEMIC GRANDISOL. AN IMPROVED CONVENIENT PROCEDURE

(+/-) Grandisol has been stereoselectively synthesized in a 31 percent overall yield by a practical and convenient procedure employing the Salomon photobicyclization as the key-step.

Practical Preparation of Bicyclohept-3-en-6-ones and its Utilisation in Stereoselective Total Synthesis of Grandisol and Lineatin via a Versatile Intermediate.

New and efficient stereoselective total syntheses have been devised for racemic grandisol and lineatin, two important components of pheromonic blends.They are based on the utilisation of 1,4-dimethylbicyclohept-3-en-6-one as a pivotal intermediate.This compound, as well as other bicyclohept-3-en-6-ones, are now easily available by a practical bicyclization of the corresponding 3-hydroxy-6-alkenoic acids.