2973-83-3Relevant articles and documents
Synthesis of Cyclic Guanidines Bearing N-Arylsulfonyl and N-Cyano Protecting Groups via Pd-Catalyzed Alkene Carboamination Reactions
Peterson, Luke J.,Luo, Jingyi,Wolfe, John P.
, p. 2817 - 2820 (2017)
Palladium-catalyzed carboamination reactions of N-allylguanidines bearing cleavable N-cyano or N-arylsulfonyl protecting groups are described. The reactions afford cyclic guanidine products in good yield, and transformations of substrates bearing internal alkenes proceed with high diastereoselectivity. Deuterium labeling studies indicate these transformations proceed via anti-aminopalladation pathways.
Synthesis of Cyclic Guanidines via Silver-Catalyzed Intramolecular Alkene Hydroamination Reactions of N-Allylguanidines
Garlets, Zachary J.,Silvi, Mattia,Wolfe, John P.
supporting information, p. 2331 - 2334 (2016/06/09)
The silver-catalyzed hydroamination of tosyl-protected N-allylguanidines is described. These reactions provide substituted cyclic guanidines in high yields. The reactions are amenable to the construction of quaternary stereocenters as well as both monocyc
Routes to functionalized guanidines. The synthesis of guanidino diesters.
Bosin,Hanson,Rodricks,Simpson,Rapoport
, p. 1591 - 1600 (2007/10/06)
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