297752-25-1

Basic information

• Product Name: (S)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthyl phosphate
• Synonyms: (S)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthyl phosphate;(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin 4-oxide;(R)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-binaphth-2,2'-yl phosphate;(S)-4-Hydroxy-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide;(R)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-binaphth-2,2'-yl phosphate (11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin 4-oxide;(R)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthyl Hydrogen Phosphate;(R)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthyl Hydrogen Phosphate,99%e.e.;(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
• CAS NO: 297752-25-1
• Molecular Formula: C20H25O4P
• Molecular Weight: 360
• EINECS: -0
• Product Categories: Apis
• Mol File: 297752-25-1.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 579.7±60.0 °C(Predicted)
• Appearance: white to light-yellow/Powder
• Density: 1.38
• Storage Temp.: Inert atmosphere,Room Temperature
• PKA: 1.19±0.20(Predicted)
• CAS DataBase Reference: (S)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthyl phosphate(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthyl phosphate(297752-25-1)
• EPA Substance Registry System: (S)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthyl phosphate(297752-25-1)

Safety Data

• Hazardous Substances Data: 297752-25-1(Hazardous Substances Data)

Usage

General Description

(S)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthyl phosphate, also known as EHDP, is a chemical compound with the molecular formula C26H30O4P. It is often used as a flame retardant and plasticizer in various industries, including the manufacturing of plastic and rubber products. EHDP is a white, crystalline powder that is insoluble in water but soluble in organic solvents. It is known for its high thermal stability and effectiveness at reducing the flammability of materials. EHDP is also commonly used in the production of electrical components and circuit boards, as well as in the construction and automotive industries. However, there is increasing concern about the potential environmental and health hazards associated with EHDP, leading to its restriction and regulation in some regions.

Upstream product

• 39648-65-2 (R)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthalene-2,2'-diyl phosphoric acid chloride 
• 39648-74-3 (Ra)-5,6,7,8,5',6',7',8'-octahydro-[1,1']binaphthalenyl-2,2'-diol 
• 35193-63-6 (S)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate 
• 39648-74-3 (S)-5,5',6,6',7,7',8,8'-octahydro-1,1'-bi-2-naphthol 

Relevant articles and documents

Direct Interconversion of BINOL and H8-BINOL-Based Chiral Br?nsted Acids Using Single-Step Red/Ox Manipulations

A direct single-step hydrogenation of BINOL-based chiral phosphoric acids, N-triflyl phosphoramides, and disulfonimides to the corresponding H8-BINOL Br?nsted acids in excellent yields and chemoselectivities is described. In addition, the conditions for t

Facile and efficient enantioselective strecker reaction of ketimines by chiral sodium phosphate

A facile and efficient enantioselective Strecker reaction of ketimines catalyzed by a chiral alkali-metal salt has been developed. When 10 mol% BNPNa (BNP=1,1'-binaphthyl-2,2'-diylphosphate) prepared in situ and 10 mol% para-tert-butylortho-adamantylphenol (PBAP) were introduced into the reaction, up to 96% yield and up to 95% ee (ee=enantiomeric excess) were obtained. Both aliphatic and aromatic ketimines, especially sterically bulky cyclic ketimines derived from β-acetonaphthone, α-indanone, and α-tetralone were found suitable for this reaction. On the basis of the experimental results and previous reports, trimethylsilyl cyanide (TMSCN) was indicated to be the real reactive nucleophile despite the existence of PBAP, and a possible working model was proposed to explain the origin of the asymmetric induction. The facile availability of 1,1'-binaphthyl-2,2'-diylphosphoric acid (BNPH) and the simplicity of the procedure are beneficial for practical applications.