29780-80-1

Basic information

• Product Name: <(benzyloxycarbonyl)methylamino>-1-deoxy-D-glucitol
• CAS NO: 29780-80-1
• Molecular Weight: 329.35
• Mol File: 29780-80-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: <(benzyloxycarbonyl)methylamino>-1-deoxy-D-glucitol(CAS DataBase Reference)
• NIST Chemistry Reference: <(benzyloxycarbonyl)methylamino>-1-deoxy-D-glucitol(29780-80-1)
• EPA Substance Registry System: <(benzyloxycarbonyl)methylamino>-1-deoxy-D-glucitol(29780-80-1)

Safety Data

• Hazardous Substances Data: 29780-80-1(Hazardous Substances Data)

Upstream product

• 6284-40-8 1-deoxy-1-(methylamino)-D-glucitol 
• 501-53-1 benzyl chloroformate 

Downstream Products

• 29780-83-4 2,3,4,5,6-penta-O-acetyl-1-<(benzyloxycarbonyl)methylamino>-1-deoxy-D-glucitol 

Relevant articles and documents

THE PHTHALATION OF 2-AMINO-2-DEOXY-D-GLUCOSE AND N-METHYL-1-AMINO-1-DEOXY-D-GLUCITOL; CONVERSION OF THE PRODUCTS TO ORGANOTIN DERIVATIVES. A READY MIGRATION OF ACETYL FROM OXYGEN TO NITROGEN UNDER NEUTRAL CONDITIONS

N-Phthalation of 3-amino-3-deoxy-D-glucose was followed by replacement of the acidic proton by tributyl- and triphenylstannyl groups.A similar reaction with 1-(methylamino)-1-deoxy-D-glucitol failed and successive treatment with benzyl chloroformate and acetic anhydride followed by catalytic hydrogenation showed that a 1,4-O->N acetyl migration had occured.Phthalation and stannylation succeeded under different conditions.