29869-86-1

Basic information

• Product Name: 2-Butanone, 4-(4-chlorophenyl)-4-phenyl-
• CAS NO: 29869-86-1
• Molecular Formula: C16H15ClO
• Molecular Weight: 258.748
• Mol File: 29869-86-1.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: 2-Butanone, 4-(4-chlorophenyl)-4-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butanone, 4-(4-chlorophenyl)-4-phenyl-(29869-86-1)
• EPA Substance Registry System: 2-Butanone, 4-(4-chlorophenyl)-4-phenyl-(29869-86-1)

Safety Data

• Hazardous Substances Data: 29869-86-1(Hazardous Substances Data)

Upstream product

• 108-90-7 chlorobenzene 
• 1896-62-4 (E)-benzalacetone 
• 637-87-6 1-Chloro-4-iodobenzene 
• 122-57-6 1-Phenylbut-1-en-3-one 
• 673-41-6 p-chlorobenzenediazonium tetrafluoroborate 
• 1802-38-6 4-chlorophenylmercury chloride 
• 71-43-2 benzene 
• 18218-20-7 1-(4-chlorophenyl)-1-phenylethene 
• 135636-66-7 butane-2,3-dione mono-oxime 
• 17333-85-6 4-chlorophenyldiazonium salt 
• 120-80-9 benzene-1,2-diol 
• 30626-03-0 (3E)-4-(4-chlorophenyl)-3-buten-2-one 
• 80-17-1 benzenesufonyl hydrazide 
• 104-88-1 4-chlorobenzaldehyde 

Downstream Products

• 5409-60-9 4,4-diphenylbutan-2-one 
• 92208-09-8 1-Chloro-4-(3,3-dimethoxy-1-phenyl-butyl)-benzene 

Relevant articles and documents

Photocatalytic Hydroacylation of Alkenes by Directly Using Acyl Oximes

Acyl oximes are directly used as the acyl radical precursors in the hydroacylation reactions for the first time. In this work, acyl radicals can be effectively generated via β-scission of a phosphoranyl radical under photocatalytic conditions. As a result, the hydroacylation of alkenes triggered by the resulting acyl radicals leads to facile syntheses of a range of valuable ketones.

Palladium(II) Acetate Catalyzed Reductive Heck Reaction of Enones; A Practical Approach

A surprisingly practical Pd(OAc)2 or Pd(TFA)2-catalyzed reductive Heck reaction between aryl iodides and α,β-unsaturated ketones is described using N,N-diisopropylethylamine (DIPEA, Hünigs base) as the reductant. In general, 1 mol % of Pd(OAc)2 is sufficient to afford good yields using electron-rich or halogen-substituted aryl iodides. Electron-deficient aryl iodides preferentially give homocoupling. Enones containing aryl or bulky substituents on the β-carbon react smoothly, producing mainly reductive Heck product, whereas enones with alkyl substituents on the β-carbon afford a mixture of reductive Heck and Heck product. Deuterium labeling experiments show that the reaction is a bona fide reductive Heck reaction and exclude a Heck reaction-conjugate reduction cascade. Deeply DIPEA about... A palladium-catalyzed reductive Heck reaction of aryl iodides to α,β-unsaturated ketones is described using N,N diisopropylethylamine (DIPEA, Hünigs base) as the reductant. A deuterium labeling study shows that the reaction is a bona fide reductive Heck reaction and excludes a Heck reaction-conjugate reduction cascade.

Palladium-catalyzed desulfitative addition of sodium sulfinates with α,β-unsaturated carbonyl compounds

A palladium-catalyzed desulfitative conjugate addition of sodium sulfinates with α,β-unsaturated carbonyl compounds is described. The reaction showed very good selectivity and tolerated a wide range of functionalities under an atmosphere of argon.