29912-59-2

Basic information

• Product Name: N,N-dimethyl-N′-(4-nitrophenylsulfonyl)formimidamide
• Synonyms: N,N-dimethyl-N′-(4-nitrophenylsulfonyl)formimidamide
• CAS NO: 29912-59-2
• Molecular Weight: 257.27
• Mol File: 29912-59-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: N,N-dimethyl-N′-(4-nitrophenylsulfonyl)formimidamide(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-dimethyl-N′-(4-nitrophenylsulfonyl)formimidamide(29912-59-2)
• EPA Substance Registry System: N,N-dimethyl-N′-(4-nitrophenylsulfonyl)formimidamide(29912-59-2)

Safety Data

• Hazardous Substances Data: 29912-59-2(Hazardous Substances Data)

Upstream product

• 73901-01-6 p-nitrobenzenesulfonyl azide 
• 10448-42-7 dimethyl-styryl-amine 
• 68-12-2 N,N-dimethyl-formamide 
• 98-74-8 4-Nitrobenzenesulfonyl chloride 
• 4009-06-7 (4-nitro-N-((4-nitrophenyl)sulfonyl)benzenesulfonamide) 
• 6325-93-5 p-nitrobenzenesulfonamide 
• 4837-49-4 4-nitro-benzenesulfonic acid-(trichlorophosphoranyliden-amide) 
• 25818-74-0 1,1-dichloromethyl-N,N-dimethylamine 
• 24588-22-5 N,N-dichloro-4-nitrobenzenesulfonamide 

Relevant articles and documents

N -Sulfonyl acetylketenimine as a highly reactive intermediate for the synthesis of N -sulfonyl amidines

A highly reactive intermediate N-sulfonyl acetylketenimine was generated from a 3-butyn-2-one participating CuAAC/ring-opening method. Its high reactivity due to bearing two EWGs allowed us to offer the first example of a reaction between ketenimine and amide to synthesize N-sulfonyl amidines efficiently.

Mild reductive functionalization of amides into N-sulfonylformamidines

The development of a protocol for the reductive functionalization of amides into N-sulfonylformamidines is reported. The one-pot procedure is based on a mild catalytic reduction of tertiary amides into the corresponding enamines by the use of Mo(CO)6 (molybdenum hexacarbonyl) and TMDS (1,1,3,3-tetramethyldisiloxane). The formed enamines were allowed to react with sulfonyl azides to give the target compounds in moderate to good yields.

Direct condensation of sulfonamide and formamide: NaI-catalyzed synthesis of N-sulfonyl formamidine using TBHP as oxidant

A new N-sulfonyl formamidine synthesis was developed via NaI-catalyzed direct condensation of sulfonamide and formamide. The green methodology is featured by high atom economy, easily available starting materials, the lack of need for a transition-metal c