29917-12-2Relevant articles and documents
First kinetic discrimination between carbon and oxygen reactivity of enols
Garcia-Rio, Luis,Mejuto, Juan C.,Parajo, Mercedes,Perez-Lorenzo, Moises
, p. 8198 - 8205 (2008)
(Chemical Equation Presented) Nitrosation of enols shows a well-differentiated behavior depending on whether the reaction proceeds through the carbon (nucleophilic catalysis is observed) or the oxygen atom (general acid-base catalysis is observed). This is due to the different operating mechanisms for C- and O-nitrosation. Nitrosation of acetylacetone (AcAc) shows a simultaneous nucleophilic and acid-base catalysis. This simultaneous catalysis constitutes the first kinetic evidence of two independent reactions on the carbon and oxygen atom of an enol. The following kinetic study allows us to determine the rate constants for both reaction pathways. A similar reactivity of the nucleophilic centers with the nitrosonium ion is observed.
Synthesis and spectroscopic studies of trans-bis-(3,5-dimethyl-4-nitrosopyrazole) dimer
Al-Shamkhani, Zeki A. Nasir,Essa, Ali Hashem
, p. 5547 - 5550 (2007)
Bis-(3,5-dimethyl-4-nitrosopyrazole) dimer was prepared by reaction of acetyl acetone with nitrous acid and condensation with hydrazine. Spectroscopic techniques, including IR, UV, 1H NMR, and 13C NMR, and CHN analysis were used to identify the product.
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White,D.A.
, p. 233 - 243 (1971)
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Reaction of 1,3-Dicarbonyl Compounds with Nitryl Chloride
Prostenik, Mladen V.,Dumic, Miljenko,Bosnjak, Nada
, p. 771 - 774 (1980)
Reaction of 1,3-dicarbonyl compounds with nitryl chloride through substitution on the activated methylene group, resulted in the formation of chloro, dichloro and oximino derivatives. - Keywords: 3-Oxobutanoic acid ethyl ester; 2,4-Petanedione; reaction with nitryl chloride
Octanitropyrazolopyrazole: A gem-trinitromethyl based green high-density energetic oxidizer
Mohammad, Khaja,Thaltiri, Vikranth,Kommu, Nagarjuna,Vargeese, Anuj A.
supporting information, p. 12945 - 12948 (2020/11/07)
Environmental concerns demand the replacement of ammonium perchlorate (AP) by a green oxidizer in composite propellants. Herein, we report the synthesis and characterization of a novel green high-density energetic oxidizer octanitropyrazolopyrazole (ONPP). With its high specific impulse (256 s), high density (1.997 g cm-3) and good thermal stability (160 °C), ONPP can potentially replace AP. This journal is
A phosphine-mediated synthesis of 2,3,4,5-tetra-substituted N-hydroxypyrroles from α-oximino ketones and dialkyl acetylenedicarboxylates under ionic liquid green-media
Shahvelayati, Ashraf S.,Ghazvini, Maryam,Yadollahzadeh, Khadijeh,Delbari, Akram S.
, p. 14 - 18 (2018/06/19)
Background: The development of multicomponent reactions (MCRs) in the presence of task-specific ionic liquids (ILs), used not only as environmentally benign reaction media, but also as catalysts, is a new approach that meet with the requirements of sustainable chemistry. In recent years, the use of ionic liquids as a green media for organic synthesis has become a chief study area. This is due to their unique properties such as non-volatility, non-flammability, chemical and thermal stability, immiscibility with both organic compounds and water and recyclability. Ionic liquids are used as environmentally friendly solvents instead of hazardous organic solvents. Objective: We report the condensation reaction between α-oximinoketone and dialkyl acetylene dicarboxylate in the presence of triphenylphosphine to afford substituted pyrroles under ionic liquid conditions in good yields. Result: Densely functionalized pyrroles was easily prepared from reaction of α-oximinoketones, dialkyl acetylene dicarboxylate in the presence of triphenylphosphine in a quantitative yield under ionic liquid conditions at room temperature. Conclusion: In conclusion, ionic liquids are indicated as a useful and novel reaction medium for the selective synthesis of functionalized pyrroles. This reaction medium can replace the use of hazardous organic solvents. Easy work-up, synthesis of polyfunctional compounds, decreased reaction time, having easily available-recyclable ionic liquids, and good to high yields are advantages of present method.