300397-31-3

Basic information

• Product Name: 2-(benzothiazol-2-ylthio)-1-(4-methylphenyl)propan-1-ol
• Synonyms: 2-(benzothiazol-2-ylthio)-1-(4-methylphenyl)propan-1-ol
• CAS NO: 300397-31-3
• Molecular Weight: 315.46
• Mol File: 300397-31-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(benzothiazol-2-ylthio)-1-(4-methylphenyl)propan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(benzothiazol-2-ylthio)-1-(4-methylphenyl)propan-1-ol(300397-31-3)
• EPA Substance Registry System: 2-(benzothiazol-2-ylthio)-1-(4-methylphenyl)propan-1-ol(300397-31-3)

Safety Data

• Hazardous Substances Data: 300397-31-3(Hazardous Substances Data)

Upstream product

• 106296-62-2 2-benzothiazol-2-ylthio(trimethylsilyl)ethanol 
• 104-87-0 4-methyl-benzaldehyde 
• 106296-67-7 1-(benzothiazol-2-ylthio)-1-(trimethylsilyl)ethane 
• 149-30-4 2-thioxo-3H-1,3-benzothiazole 

Downstream Products

• 17626-88-9 2-(tert-butyl)benzo[d]thiazole 
• 300395-17-9 2-mercapto-1-(4-methylphenyl)-1-propan-1-ol 

Relevant articles and documents

Reactions of (Benzothiazol-2-ylthio)(trimethylsilyl)methane. A General Method for α-Mercaptoalkylation by Alkylation and Alkylative Desilylation

Readily available (benzothiazol-2-ylthio)(trimethylsilyl)methane (2a) provides a convenient synthon for HSCH2- and enables the general conversions RR'CO -> RR'C(OH)CH(SH)R'' and RBr -> RCH(SH)SiMe3.The lithium derivative of 2a reacts with aldehydes and ketones to give Peterson olefination products which are protected vinyl mercaptans converted into vinyl mercaptans by reaction with methyllithium.This overall conversion is RR'CO -> RR'C:CHSH.