3007-19-0 Usage
Description
(4-tert-butylcyclohexylidene)bis[tert-butyl] peroxide, also known as a free radical initiator, is a chemical compound derived from peroxides. It is characterized by its clear, colorless liquid appearance with a faint odor. (4-tert-butylcyclohexylidene)bis[tert-butyl] peroxide is insoluble in water and is highly reactive, which makes it prone to spontaneous decomposition, posing significant fire and explosion hazards. Due to its reactivity, it is crucial to handle this compound with extreme caution, using appropriate protective measures such as gloves, goggles, and a respirator, and to store it in a cool, well-ventilated area away from heat and sources of ignition.
Uses
Used in Polymer Industry:
(4-tert-butylcyclohexylidene)bis[tert-butyl] peroxide is used as a free radical initiator for the polymerization of unsaturated monomers. Its high reactivity allows for efficient initiation of polymerization reactions, which is crucial in the production of various polymers with specific properties and applications.
Used in Chemical Synthesis:
In addition to its role in the polymer industry, (4-tert-butylcyclohexylidene)bis[tert-butyl] peroxide can also be utilized in other chemical synthesis processes where free radical reactions are required. Its ability to generate free radicals can facilitate various chemical transformations, making it a valuable compound in the synthesis of different products.
Safety Precautions:
Given the hazardous nature of (4-tert-butylcyclohexylidene)bis[tert-butyl] peroxide, it is essential to follow strict safety protocols when handling and storing this compound. This includes wearing appropriate personal protective equipment (PPE) such as gloves, goggles, and a respirator to prevent exposure to the compound. Additionally, it should be stored in a cool, well-ventilated area, away from heat and sources of ignition to minimize the risk of spontaneous decomposition and potential accidents.
Check Digit Verification of cas no
The CAS Registry Mumber 3007-19-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,0,0 and 7 respectively; the second part has 2 digits, 1 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 3007-19:
(6*3)+(5*0)+(4*0)+(3*7)+(2*1)+(1*9)=50
50 % 10 = 0
So 3007-19-0 is a valid CAS Registry Number.
InChI:InChI=1/C18H36O4/c1-15(2,3)14-10-12-18(13-11-14,21-19-16(4,5)6)22-20-17(7,8)9/h14H,10-13H2,1-9H3
3007-19-0Relevant articles and documents
The effect of iodine on the peroxidation of carbonyl compounds
Zmitek, Katja,Zupan, Marko,Stavber, Stojan,Iskra, Jernej
, p. 6534 - 6540 (2008/02/10)
(Chemical Equation Presented) Peroxidation of ketones and aldehydes with iodine as a catalyst was studied. Ketones reacted with 30% aq hydrogen peroxide in the presence of 10 mol % of iodine to yield gem-dihydroperoxides in acetonitrile and hydroperoxyketals in methanol. The yield of hydroperoxidation of various cyclic ketones was 60-98%, including androstane-3,17-dione, while acyclic ketones were converted with a similar efficiency. Aromatic aldehydes were also converted to gem-dihydroperoxides with hydrogen peroxide and iodine as catalyst in acetonitrile and to hydroperoxyacetal in methanol, while the reactivity of aliphatic ones remained the same as in noncatalyzed reactions. tert-Butylhydroperoxide reacted in a similar manner, giving the corresponding perether derivatives. A study was also made of the relative kinetics of dihydroperoxidation from which the Hammet equation gave a reaction constant (ρ) of -2.76, indicating the strong positive charge development in the transition state and the important role of rehybridization in the conversion of hydroperoxyhemiketal to gem-dihydroperoxide. In acetonitrile, the iodine catalyst is apparently able to discriminate between the elimination of a hydroxy, methoxy, and hydroperoxy group and addition of water, methanol, and H2O2 to a carbonyl group.
