3007-73-6

Basic information

• Product Name: N-decylaniline
• Synonyms: N-Decylaniline
• CAS NO: 3007-73-6
• Molecular Formula: C₁₆H₂₇N
• Molecular Weight: 233.3923
• Mol File: 3007-73-6.mol
• Article Data: 23

Chemical Properties

• Boiling Point: 342.5°C at 760 mmHg
• Flash Point: 162.1°C
• Density: 0.906g/cm³
• Vapor Pressure: 7.5E-05mmHg at 25°C
• Refractive Index: 1.514
• PKA: 5.06±0.50(Predicted)
• CAS DataBase Reference: N-decylaniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-decylaniline(3007-73-6)
• EPA Substance Registry System: N-decylaniline(3007-73-6)

Safety Data

• Hazardous Substances Data: 3007-73-6(Hazardous Substances Data)

Upstream product

• 112-31-2 caprinaldehyde 
• 98-95-3 nitrobenzene 
• 2016-57-1 1-aminodecane 
• 108-90-7 chlorobenzene 
• 764-93-2 1-decyne 
• 62-53-3 aniline 
• 112-13-0 n-decanoyl chloride 
• 15473-32-2 decananilide 
• 41233-29-8 methanesulfonic acid decyl ester 
• 112-29-8 1-bromo dodecane 
• 103-70-8 Formanilid 
• 112-30-1 1-Decanol 

Downstream Products

• 1311478-34-8 C₄₀H₆₆N₄O₂ 
• 55239-88-8 C₁₇H₂₆ClNO 

Relevant articles and documents

Switchable Imine and Amine Synthesis Catalyzed by a Well-Defined Cobalt Complex

Switchable imine and amine synthesis catalyzed by a tripodal ligand-supported well-defined cobalt complex is presented herein. A large variety of primary alcohols and amines were selectively converted to imines or amines in good to excellent yields. It is discovered that the base plays a crucial role on the selectivity. A catalytic amount of base leads to the imine formation, while an excess loading of base results in the amine product. This strategy on product selectivity also strongly depends on the organometallic catalysts in use. We expect that the present study could provide useful insights toward selective organic synthesis and catalyst design.

Bidentate geometry-constrained iminopyridyl nickel-catalyzed synthesis of amines or imines via borrowing hydrogen or dehydrogenative condensation

The efficient Ni-catalyzed N-alkylation of various anilines with alcohols via borrowing hydrogen is reported using a bidentate geometry-constrained iminopyridyl nickel complex as the catalyst. Substituted benzylic alcohols and short/long chain aliphatic alcohols could be applied as the alkylation sources to couple with aromatic and heteroaromatic amines to give a diverse set of N-alkylation outcomes in moderate to excellent yields. The nickel catalytic system was also suitable for aliphatic amines, selectively delivering the corresponding imines via an acceptorless dehydrogenative condensation strategy.

C–N Cross-coupling Reactions of Amines with Aryl Halides Using Amide-Based Pincer Nickel(II) Catalyst

Abstract: An approach to C–N cross-coupling reactions of aryl halides with amines in the presence of an amide-based pincer nickel(II) catalyst (2) is described. For 3?h reactions at 110?°C with 0.2?mol% catalyst, aryl bromides gave higher turnover numbers (TON) than the corresponding chlorides or iodides. Both primary and secondary amines could be used with the former giving higher TON. However, sterically hindered amines showed lower TON. In elucidating the mechanism of this nickel complex-catalyzed C–N cross coupling reaction it was found that the rate of reaction was unchanged in the presence of radical quenchers and a plausible Ni(I)–Ni(III) pathway is proposed. Graphic Abstract: [Figure not available: see fulltext.]Nickel pincer catalyst proved to be excellent catalyst for the C-N cross-coupling reaction with the high turnover number (TON) for 1° and 2° amines and different nonactivated aryl halides under optimum conditions.