3021-73-6Relevant articles and documents
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Pirozhkov,S.D. et al.
, (1977)
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Warner,P.M. et al.
, p. 3773 - 3778 (1977)
Studies in Alicyclic Compounds: Part VII - Koch-Haaf Carboxylation of 1-Cycloalkylcycloalkanols
Rao, R. R.,Bhattacharya, S.
, p. 207 - 209 (2007/10/02)
The Koch-Haaf carboxylation (K-H-C) of 1-cycloalkylcyclopentanols (Ia and Ib) and 1-cycloalkylcyclohexanols (VIa and VIb) has been investigated.In the case of 1-cycloalkylcyclopentanols (Ia and Ib), K-H-C results in the formation of rearranged tertiary (30) bridgehead acids (Va and Vb) providing interesting examples of ring expansion reactions, whereas K-H-C of 1-cycloalkylcyclohexanols (VIa and VIb) furnishes the corresponding 30 carboxylic acids (VIIIa and VIIIb) in good yields.