302351-89-9Relevant articles and documents
2,3-Difunctionalized Indoles via Radical Acylation or Trifluoromethylation of ortho-Alkynylphenyl Isonitriles
Leifert, Dirk,Weidlich, Frauke,Adler, Florin,Daniliuc, Constantin G.,Alasmary, Fatmah A.,Studer, Armido
, p. 284 - 288 (2021/12/27)
A radical cascade to 2,3-disubstituted indoles proceeding via acylation or trifluoromethylation of ortho-alkynylphenyl isonitriles is presented. In these cascades, two C–C bonds and one C–O bond are formed using an inexpensive oxidant and a catalytic copp
Cascades to substituted indoles
Rainier, Jon D.,Kennedy, Abigail R.
, p. 6213 - 6216 (2007/10/03)
This paper describes the synthesis of dithioindoles from the free-radical cyclizations of arylisonitriles having pendant alkynes. Also described is the synthesis of substituted indoles and spiro-fused indoles from the coupling of dithioindoles with active hydrogen-containing compounds.