30346-27-1

Basic information

• Product Name: (E)-2-(3,3-Dimethylcyclohexylidene)-ethanol
• Synonyms: (E)-2-(3,3-Dimethylcyclohexylidene)-ethanol;GrandlureII,E-Isomerof;1-[(E)-2-Hydroxyethylidene]-3,3-dimethylcyclohexane;Ethanol, 2-(3,3-dimethylcyclohexylidene)-, (2E)-;(2E)-2-(3,3-Dimethylcyclohexylidene)-ethanol;(E)-Grandlure II
• CAS NO: 30346-27-1
• Molecular Formula: C₁₀H₁₈O
• Molecular Weight: 154.24932
• Mol File: 30346-27-1.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 212.7±8.0℃ (760 Torr)
• Flash Point: 90.0±8.3℃
• Appearance: /
• Density: 0.966±0.06 g/cm3 (20 ºC 760 Torr)
• Refractive Index: 1.4774 (22℃)
• CAS DataBase Reference: (E)-2-(3,3-Dimethylcyclohexylidene)-ethanol(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-2-(3,3-Dimethylcyclohexylidene)-ethanol(30346-27-1)
• EPA Substance Registry System: (E)-2-(3,3-Dimethylcyclohexylidene)-ethanol(30346-27-1)

Safety Data

• Hazardous Substances Data: 30346-27-1(Hazardous Substances Data)

Usage

Description

(E)-2-(3,3-Dimethylcyclohexylidene)-ethanol, also known as dihydrotoxyl, is a chemical compound characterized by its molecular formula C10H20O. It is a clear, colorless liquid with a pleasant odor and is recognized for its versatile applications across different industries.

Uses

Used in Fragrance Industry:
(E)-2-(3,3-Dimethylcyclohexylidene)-ethanol is used as a fragrance ingredient for its pleasant odor, enhancing the scent profiles of various products in the fragrance industry.
Used in Pharmaceutical and Personal Care Products:
(E)-2-(3,3-Dimethylcyclohexylidene)-ethanol is used as an active ingredient for its antifungal and antibacterial properties, making it a valuable addition to pharmaceutical and personal care products to ensure cleanliness and prevent infections.
Used in Industrial Applications:
(E)-2-(3,3-Dimethylcyclohexylidene)-ethanol is used as a solvent in various industrial processes, leveraging its chemical properties to facilitate different manufacturing and production tasks.
Safety Precautions:
When handling (E)-2-(3,3-Dimethylcyclohexylidene)-ethanol, it is important to take safety precautions due to its potential to cause skin irritation. Additionally, it is crucial to avoid ingestion or inhalation, as it could be harmful. Proper protective equipment and handling procedures should be followed to minimize risks.

InChI:InChI=1/C10H18O/c1-8(11)9-5-4-6-10(2,3)7-9/h11H,4-7H2,1-3H3/b9-8-

Upstream product

• 116440-82-5 tert-Butyl-{2-[3,3-dimethyl-cyclohex-(E)-ylidene]-ethoxy}-dimethyl-silane 
• 82528-39-0 6-phenylthio-2-ochtoden-1-ol 
• 82528-42-5 (2E)-1-hydroxy-2-ochtoden-6-one 
• 116440-79-0 ((Z)-8-Bromo-3-iodo-5,5-dimethyl-oct-2-enyloxy)-tert-butyl-dimethyl-silane 
• 116440-76-7 5,5-Dimethyl-oct-7-en-2-yn-1-ol 
• 70473-42-6 [1-(1-Chloro-1-methyl-ethyl)-4-methylene-hex-5-enylsulfanyl]-benzene 
• 82528-37-8 1-chloro-6-phenylthio-2-ochtodene 
• 30346-22-6 3,3-Dimethyl-1-hydroxy-cyclohexylessigsaeure 
• 5629-80-1 (1-hydroxy-3,3-dimethyl-cyclohexyl)-acetic acid ethyl ester 
• 112381-71-2 (E)-8-Iodo-7,7-dimethyl-3-tributylstannanyl-oct-2-enoic acid methyl ester 
• 82528-38-9 1-acetoxy-6-phenylthio-2-ochtodene 
• 82528-40-3 (EZ)-6-hydroxy-2-ochtoden-1-yl trifluoroacetate 
• 123-35-3 7-methyl-3-methene-1,6-octadiene 
• 121618-03-9 (E)-6-oxo-2-ochtoden-1-yl 3,5-dinitrobenzoate 

Downstream Products

• 20489-81-0 5-(3,3-dimethyl-cyclohexylidene)-pent-3-en-2-one 
• 123433-93-2 (Z)-1-ethylidene-3,3-dimethylcyclohexane 
• 95495-41-3 (E)-3-<3-(3-furyl)propylidene>-1,1-dimethylcyclohexane 
• 95495-43-5 (Z)-3-<3-(3-furyl)propylidene>-1,1-dimethylcyclohexane 
• 95495-40-2 (E)-3-<3-(3-furyl)-2-(p-tolylsulfonyl)propylidene>-1,1-dimethylcyclohexane 
• 95495-39-9 (E)-1-(p-tolylsulfonyl)-2-ochtodene 
• 95495-56-0 3-[(Z)-3-(5,5-Dimethyl-cyclohex-1-enyl)-allyl]-furan 
• 84510-69-0 1-<1-acetoxy-3-(3-furyl)-2-tosylpropyl>-5,5-dimethylcyclohexene 
• 84510-68-9 3-(3-furyl)-1-(5,5-dimethyl-1-cyclohexenyl)-2-tosyl-1-propanol 
• 84510-67-8 1-<3-(3-furyl)-2-tosylpropionyl>-5,5-dimethylcyclohexene 
• 84510-64-5 2-hydroxy-3-ochtodene-1-yl tosylate 
• 84510-65-6 2-oxo-3-ochtodene-1-yl tosylate 
• 84510-66-7 1-tosyl-3-ochtodene-2-one 
• 84510-63-4 3-ochtodene-1,2-diol 

Relevant articles and documents

Pheromone Synthesis, CXV. - Synthesis of (Z)-2-Ochtoden-1-ol, (E)-2-Ochtoden-1-al, and (Z)-2-Ochtoden-1-al, the Pheromone Components of the Boll Weevil (Anthonomus grandis)

The synthesis of geometrically pure (Z)-2-ochtoden-1-ol (1), (E)-2-ochtoden-1-al (2), and (Z)-2-ochtoden-1-al (3) was achieved starting from myrcene.

THE STEREOSPECIFIC FORMATION OF AN EXOCYCLIC ALKENE BY A CONSECUTIVE RADICAL CYCLIZATION-ELEIMINATION

The iodovinylstannanes 4 and 5 were prepared by the conjugate addition of the tri-n-butyltin moiety to a substituted propiolic ester.Compounds 4 and 5 underwent a radical cyclization-elimination reaction to stereospecifically generate an exocyclic alkene.

NEW OCHTODANE SYNTHESES FROM MYRCENE

The ochtodane skeleton is formed stereoselectively from myrcene via acid-catalyzed cyclization of the benzenesulfenyl chloride adduct and the epoxide in a biogenetic type fashion.Its application to the syntheses of two ochtodane-type monoterpenes, an aldehyde component of the boll weevil pheromone and a diol found in the red alga Ochtodes crockeri, is reported.