30405-75-5

Basic information

• Product Name: Benzene, 1,2-dimethoxy-4-(1-methylethenyl)-
• CAS NO: 30405-75-5
• Molecular Formula: C11H14O2
• Molecular Weight: 178.231
• Mol File: 30405-75-5.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: Benzene, 1,2-dimethoxy-4-(1-methylethenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,2-dimethoxy-4-(1-methylethenyl)-(30405-75-5)
• EPA Substance Registry System: Benzene, 1,2-dimethoxy-4-(1-methylethenyl)-(30405-75-5)

Safety Data

• Hazardous Substances Data: 30405-75-5(Hazardous Substances Data)

Upstream product

• 1779-49-3 Methyltriphenylphosphonium bromide 
• 1131-62-0 1-(3,4-dimethoxyphenyl)ethanone 
• 67-71-0 dimethylsulfone 
• 93-03-8 (3,4-dimethoxyphenyl)methanol 
• 2065-66-9 methyl-triphenylphosphonium iodide 
• 94824-20-1 1-(3,4-Dimethoxy-phenyl)-aethyl-p-tolyl-sulfon 
• 75-16-1 methylmagnesium bromide 
• 1206451-03-7 2-(2-bromo-4,5-dimethoxyphenyl)-2-methylpropanal 
• 50766-67-1 2-(3,4-dimethoxyphenyl)-1,3-dithiane 
• 89980-69-8 3,4-dimethoxyphenylmagnesium bromide 
• 67-64-1 acetone 
• 109125-11-3 <2-(3,4-dimethoxyphenyl)prop-1-en-3-yl>trimethylammonium iodide 
• 19493-09-5 Methylenetriphenylphosphorane 
• 917-64-6 methyl magnesium iodide 

Downstream Products

• 1415643-34-3 1,2-dimethoxy-4-(3-tosylprop-1-en-2-yl)benzene 
• 1424343-23-6 2-(3,4-dimethoxyphenyl)prop-2-en-1-ol 
• 1620152-27-3 ethyl (1R,2R)-2-(3,4-dimethoxyphenyl)-2-methylcyclopropanecarboxylate 
• 235417-78-4 3-(3,4-Dimethoxyphenyl)butanal 

Relevant articles and documents

1,3-Difunctionalization of β-alkyl nitroalkenes via combination of Lewis base catalysis and radical oxidation

Upon treatment with a Lewis base catalyst, β-alkyl-substituted nitroalkenes could be readily converted into allylic nitro compounds. Examples of either C-1 or C-3 functionalization methods have been reported through nitro-elimination, giving alkene products. In this work, successful 1,3-difunctionalization was achieved through a synergetic Lewis base catalysis and TBHP radical oxidation, giving vinylic alkoxyamines in good to excellent yields. This work further extended the general synthetic application of β-alkyl nitroalkenes.

Ni-Catalyzed Reductive Allylation of α-Chloroboronates to Access Homoallylic Boronates

The transition-metal-catalyzed allylation reaction is an efficient strategy for the construction of new carbon-carbon bonds alongside allyl or homoallylic functionalization. Herein we describe a Ni-catalyzed reductive allylation of α-chloroboronates to efficiently render the corresponding homoallylic boronates, which could be readily converted into valuable homoallylic alcohols or amines or 1,4-diboronates. This reaction features a broad substrate scope with good functional group compatibility that is complementary to the existing methods for the preparation of homoallylic boronates.

Single-pot access to bisorganoborinates: Applications in zweifel olefination

Zweifel olefination is a catalyst-free reaction that serves alkene functionalization. While most methods employ commercially available boron pinacol esters, we have assembled a sequence in which the two partners of the formal coupling reaction are installed successively, starting from inexpensive boron alkoxides. The in situ formation of bisorganoborinates was accomplished by consecutive reaction of two different organometallic species. This single-pot procedure represents a great advancement in the generation of organoborinates and their involvement in C-C bond formation.