30478-77-4Relevant articles and documents
Reaction products of γ-tocopherol with (E)-4-oxo-2-nonenal in acidic acetonitrile
Saito, Fumie,Iwamoto, Satoshi,Yamauchi, Ryo
, p. 168 - 174 (2010)
γ-Tocopherol was reacted with (E)-4-oxo-2-nonenal (ONE) at 37 °C in an acidic acetonitrile solution. The reaction products were isolated by reversed-phase high-performance liquid chromatography and their structures were characterized to be 5-substituted γ
Photooxygenation of azidoalkyl furans: Catalyst-free triazole and new endoperoxide rearrangement
Kazancioglu, Elif Akin,Kazancioglu, Mustafa Zahrittin,Fistikci, Meryem,Secen, Hasan,Altundas, Ramazan
supporting information, p. 4790 - 4793 (2013/10/08)
Photooxygenation of azidoalkyl furans has revealed both a novel triazole formation method and a unique endoperoxide rearrangement. The key step of this method is a 3 + 2 cycloaddion of the azide to the endoperoxide intermediate. The reduction of the peroxide bond and two subsequent C-C bond cleavages provide a triazole having a newly formed carboxylic acid functionality. The reactions are clean and efficient with yields ranging from 60% to 90%.
A novel one-pot synthesis of secondary alcohols from esters
Chae, Min Jung,Jeon, Ah Ram,Park, Jae Kyo,An, Duk Keun
experimental part, p. 1718 - 1720 (2011/04/25)
Alkylation or vinylation by using organometallic reagents after partial reduction of carboxylic esters with LDBBA gave secondary alcohols, also involving allyl alcohols, without any isolation of intermediates in good yield (54-78%).