3052-73-1Relevant articles and documents
Aryne Three-Component Coupling Involving CS2for the Synthesis of S-Aryl Dithiocarbamates
Bhattacharjee, Subrata,Deswal, Shiksha,Manoj, Niket,Jindal, Garima,Biju, Akkattu T.
supporting information, p. 9083 - 9088 (2021/11/30)
A facile synthesis of biologically important S-aryl dithiocarbamates has been demonstrated by the aryne three-component coupling involving CS2 and aliphatic amines. This transition-metal-free and mild reaction is scalable and operates with good functional group compatibility. Preliminary mechanistic experiments, including density functional theory studies, are also provided. Moreover, with 3-triflyloxybenzynes, a unique four-component coupling incorporating tetrahydrofuran was observed.
Chemoselective C–S/S–S Formation between Diaryl Disulfides and Tetraalkylthiuram Disulfides
Peng, Kang,Zhu, Hui,Liu, Xing,Peng, Han-Ying,Chen, Jin-Quan,Dong, Zhi-Bing
, p. 7629 - 7634 (2019/12/03)
An efficient C–S/S–S formation for the chemoselective synthesis of aryl dithiocarbamate (C–S formation) and aryl dialkylcarbamo(dithioperoxo)thioate (S–S formation) was studied. The chemoselectivity could be controlled by modulating the reaction temperature, base, and catalyst. The transformation features a simple reaction, easily available starting materials, high selectivity and easy performance, showing its practical synthetic value for the preparation of some potential biologically or pharmaceutically active compounds.
Synthesis of Phenyl Dithiocarbamates Starting from Sodium Dialkyldithiocarbamates and Aryl Boronic Acids: a Copper Catalyzed S-Arylation
Gao, Ming-Yuan,Xu, Wan,Zhang, Shi-Bo,Li, Yue-Sheng,Dong, Zhi-Bing
, p. 6693 - 6698 (2018/11/25)
A convenient and efficient protocol for the S-arylation of sodium dialkyldithiocarbamates was developed. With the catalysis of copper(I) bromide, sodium dialkyldithiocarbamates coupled with aryl boronic acids giving the C-S coupling products smoothly in g
