3070-40-4

Basic information

• Product Name: Peroxide, bis(1-oxo-3-phenylpropyl)
• CAS NO: 3070-40-4
• Molecular Formula: C18H18O4
• Molecular Weight: 298.339
• Mol File: 3070-40-4.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Peroxide, bis(1-oxo-3-phenylpropyl)(CAS DataBase Reference)
• NIST Chemistry Reference: Peroxide, bis(1-oxo-3-phenylpropyl)(3070-40-4)
• EPA Substance Registry System: Peroxide, bis(1-oxo-3-phenylpropyl)(3070-40-4)

Safety Data

• Hazardous Substances Data: 3070-40-4(Hazardous Substances Data)

Upstream product

• 1821-12-1 4-Phenylbutyric acid 
• 501-52-0 3-Phenylpropionic acid 
• 645-45-4 hydrocinnamic acid chloride 

Downstream Products

• 1083-56-3 1,4-diphenylbutane 
• 15719-64-9 methylammonium carbonate 
• 501-52-0 3-Phenylpropionic acid 
• 100-41-4 ethylbenzene 
• 60-12-8 2-phenylethanol 
• 28049-10-7 3-phenylpropionic acid 2-phenylethyl ester 
• 119-84-6 C₆H₄(CH₂CH₂C(O)O) 
• 103-29-7 1,1'-(1,2-ethanediyl)bisbenzene 
• 6305-31-3 2-(2-phenylethyl)-1,3-benzothiazole 
• 96719-88-9 1-(β-phenethyl)-2-phenyl-1,2,3,4-tetrahydroisoquinoline 
• 27066-35-9 (E)-1,4-diphenylbut-1-ene 
• 65845-73-0 2-methyl-4-phenethylquinoline 
• 140244-00-4 1-fluoro-1,4-diphenylbutane 

Relevant articles and documents

Development of BODIPY dyes with versatile functional groups at 3,5-positions from diacyl peroxides via Cu(ii)-catalyzed radical alkylation

An efficient Cu(ii)-catalyzed, C-H alkylation of BODIPY with a variety of alkyl diacyl peroxides has been developed for the first time, providing a late-stage and straightforward method for controllable synthesis of monoalkylated and dialkylated BODIPYs via a radical process that otherwise is difficult to obtain by literature methods. This chemo- and site-selective transformation will allow for the introduction of a variety of functionalities on the BODIPY core for highly versatile tethering to receptors and to other molecules of interest.

Decarboxylative C(sp3)?N cross-coupling of diacyl peroxides with nitrogen nucleophiles

We have disclosed a new radical-mediated decarboxylative C(sp3)?N cross-coupling of diacyl peroxides with nitrogen nucleophiles. The primary and secondary alkyl radicals derived from corresponding diacyl peroxides were generated by copper catalysis or by merging copper catalysis and photoredox catalysis, respectively. Various N-alkyl nitrogen nucleophiles, including indazoles, triazoles, indoles, purine, carbazole, anilines, and sulfonamide, were provided with a broad substrate scope and good functional group tolerance.

Radical alkylation of C(sp3)-H bonds with diacyl peroxides under catalyst-free conditions

Herein, we describe a protocol for alkylation reactions of C(sp3)-H bonds with diacyl peroxides by means of a process involving cross-coupling between an alkyl radical and an α-Aminoalkyl radical. The mild, catalyst-And additive-free conditions make this protocol superior to previously reported C(sp3)-H alkylation strategies. The protocol was applied to 1,2,3,4-Tetrahydroisoquinolines and a tetrahydro-β-carboline derivative and could be carried out on a gram scale, indicating its utility for the alkylation of late-stage synthetic intermediates.