307520-08-7Relevant articles and documents
Aminocyclodextrins to facilitate the deprotonation of 4-tert-butyl-α- nitrotoluene
Barr, Lorna,Easton, Christopher J.,Lee, Kitty,Lincoln, Stephen F.
, p. 2990 - 2993 (2005)
6A-Amino-6A-deoxy-β-cyclodextrin enhances the rate of the deprotonation of 4-terf-butyl-α-nitrotoluene. The rate constants for reaction of the cyclodextrin-bound species, kinc = 4 × 10-3, 9 × 10-3 and
Conversion of nitroalkanes into carboxylic acids via iodide catalysis in water
Marcé, Patricia,Lynch, James,Blacker, A. John,Williams, Jonathan M. J.
supporting information, p. 1013 - 1016 (2016/01/16)
We report a new method for the conversion of nitroalkanes into carboxylic acids that achieves this transformation under very mild conditions. Catalytic amounts of iodide in combination with a simple zinc catalyst are needed to give good conversions into the corresponding carboxylic acids.
Cascade formation of isoxazoles: Facile base-mediated rearrangement of substituted oxetanes
Burkhard, Johannes A.,Tchitchanov, Boris H.,Carreira, Erick M.
supporting information; experimental part, p. 5379 - 5382 (2011/07/08)
Give me five! Nitro compounds and oxetan-3-one react through an intriguing cascade sequence to give isoxazole-4-carbaldehydes using inexpensive reagents in a one-pot procedure (see scheme; Ms=methanesulfonyl). A variety of 3-substituted isoxazole-4-carbaldehydes were obtained in high overall yields.
