307980-34-3

Basic information

• Product Name: 2-Bromo-propionic acid (3aR,5R,6S,6aR)-5-benzyloxymethyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester
• Synonyms: 2-Bromo-propionic acid (3aR,5R,6S,6aR)-5-benzyloxymethyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester
• CAS NO: 307980-34-3
• Molecular Weight: 415.281
• Mol File: 307980-34-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Bromo-propionic acid (3aR,5R,6S,6aR)-5-benzyloxymethyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Bromo-propionic acid (3aR,5R,6S,6aR)-5-benzyloxymethyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester(307980-34-3)
• EPA Substance Registry System: 2-Bromo-propionic acid (3aR,5R,6S,6aR)-5-benzyloxymethyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester(307980-34-3)

Safety Data

• Hazardous Substances Data: 307980-34-3(Hazardous Substances Data)

Upstream product

• 23202-83-7 5-benzyl-1,2-O-isopropylidene-α-D-xylofuranose 
• 598-72-1 2-Bromopropionic acid 
• 100-39-0 benzyl bromide 
• 20031-21-4 1,2-O-isopropylidene-α-D-xylose 

Relevant articles and documents

Free radical allyl transfers utilizing soluble non-cross-linked polystyrene and carbohydrate scaffold supports

(matrix presented) Free radical allylations were studied using (1) soluble non-cross-linked polystyrene supports, (2) carbohydrate scaffolds, and (3) a combination of both synthetic motifs. Allylations on these custom designer supports provide easily purified products, free of tin residues. A D-xylose carbohydrate scaffold bearing a bromoester was used for a diastereoselective allyl tin transfer thermally at 80 °C and with Lewis acids. This is the first example of a diastereoselective radical reaction directed by a removable polymer-supported carbohydrate auxiliary.