308366-30-5Relevant articles and documents
Oxazoline mediated routes to a unique amino-acid, 4-amino-13-carboxy[2.2]paracyclophane, of planar chirality
Marchand, Anne,Maxwell, Anderson,Mootoo, Baldwin,Pelter, Andrew,Reid, Alicia
, p. 7331 - 7338 (2007/10/03)
Efficient syntheses leading to 4-amino-13-carboxy[2.2]paracyclophane and derivatives are described. Novel oxazolinyl[2.2]paracyclophanes are used as intermediates and the oxazolinyl and amide groups are shown to be strong ψ-geminal directing groups. Compounds with potential as catalysts have been made. (C) 2000 Elsevier Science Ltd.