30886-09-0Relevant articles and documents
Process for the preparation of 2-hydroxy-4,6-diaryl-1,3,5-triazines
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, (2008/06/13)
There is disclosed a process for the preparation of 2-hydroxy-4,6-diaryl-1,3,5-triazines, which comprises reacting the compound of formula STR1 wherein R is hydrogen, C1 -C4 alkyl or halogen, with urea, using a base selected from the class of the alkali metal hydrides, alkaline earth metal hydrides, or alkali metal amides, alkaline earth metal amides, or of the alkali metal C1 -C4 alcoholates in the presence of a polar solvent, to give the final products in a one step process in which the molar ratio of urea to base is 1:2 to 1:3 and the molar ratio of compound of formula (1) to urea is 2:1 to 5:1. 2-Hydroxy-4,6-diaryl-1,3,5-triazines are prepared in very good yield by the inventive process. The compounds are used as intermediates for the synthesis of UV absorbers.