3091-32-5

Basic information

• Product Name: TRICYCLOHEXYLTIN CHLORIDE
• Synonyms: CHLOROTRICYCLOHEXYLTIN;TRICYCLOHEXYLTIN CHLORIDE;TRICYCLOHEXYLCHLOROTIN;chlorotricyclohexyl-stannan;chlorotricyclohexylstannane;TRICYCLOHEXYL STANNIC CHLORIDE;Tricyclohexylolobic chloride;Tricyclohexyltin chloride,Chlorotricyclohexyltin
• CAS NO: 3091-32-5
• Molecular Formula: C₁₈H₃₃ClSn
• Molecular Weight: 403.62
• EINECS: 221-437-5
• Product Categories: organic tin
• Mol File: 3091-32-5.mol
• Article Data: 9

Chemical Properties

• Melting Point: 123-125 °C(lit.)
• Boiling Point: >250°C
• Flash Point: >150°C
• Appearance: /
• Vapor Pressure: 1.61E-06mmHg at 25°C
• Storage Temp.: 2-8°C
• Water Solubility: Soluble in ethanol, ether, toluene and chloroform. Insoluble in water.
• CAS DataBase Reference: TRICYCLOHEXYLTIN CHLORIDE(CAS DataBase Reference)
• NIST Chemistry Reference: TRICYCLOHEXYLTIN CHLORIDE(3091-32-5)
• EPA Substance Registry System: TRICYCLOHEXYLTIN CHLORIDE(3091-32-5)

Safety Data

• Hazard Codes: Xn,N
• Statements: 20/21/22-50/53
• Safety Statements: 26-28-61-60
• RIDADR: 3146
• WGK Germany: 3
• RTECS: WH6830000
• TSCA: Yes
• HazardClass: 6.1(b)
• PackingGroup: III
• Hazardous Substances Data: 3091-32-5(Hazardous Substances Data)

Usage

Description

TRICYCLOHEXYLTIN CHLORIDE is an organotin compound characterized by its chemical structure that features three cyclohexyl groups attached to a central tin atom, with a chloride ion as a counter ion. It is known for its unique chemical properties and potential applications in various fields.

Uses

Used in Chemical Synthesis:
TRICYCLOHEXYLTIN CHLORIDE is used as a reagent for the preparation of dicyclohexyl disulfide, which is an important intermediate in the synthesis of various organic compounds.
Used in Pharmaceutical Industry:
TRICYCLOHEXYLTIN CHLORIDE is used as a precursor in the synthesis of organotin derivatives of 2-thiophene carboxylic acid. These derivatives have potential applications as enzyme inhibitors and antibacterial agents, making them valuable in the development of new drugs for treating bacterial infections.

InChI:InChI=1/3C6H11.ClH.Sn/c3*1-2-4-6-5-3-1;;/h3*1H,2-6H2;1H;/q;;;;+1/p-1/rC18H33ClSn/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h16-18H,1-15H2

Upstream product

• 7790-99-0 Iodine monochloride 
• 1449-55-4 Tetracyclohexyl-stannan 
• 75-77-4 chloro-trimethyl-silane 
• 13121-70-5 cyhexatin 
• 96868-33-6 1,4-bis(tricyclohexylstannyl)benzene 
• 7646-78-8 tin(IV) chloride 
• 931-51-1 cyclohexylmagnesiumchloride 
• 3023-92-5 tris(cyclohexyl)tin bromide 
• 542-18-7 cyclohexyl chloride 
• 931-50-0 cyclohexylmagnesium bromide 
• 110-83-8 cyclohexene 
• 3342-69-6 dicyclohexyltin dichloride 
• 20204-08-4 tris(cyclohexyl)(phenyl)stannane 
• 13121-83-0 Cy₃SnCH₂CHCH₂ 

Downstream Products

• 2550-40-5 1,2-dicyclohexyl disulfide 
• 68974-04-9 4,4'-bis-(Tricyclohexylstannoxy)-diphenylsulfide 
• 55203-29-7 4,4'-bis-(Tricyclohexylstannoxy)-diphenylsulfone 
• 13121-86-3 tris(cyclohexyl)tin iodide 
• 5837-26-3 bis(tris(cyclohexyl)tin) oxide 
• 13121-70-5 cyhexatin 
• 13121-83-0 Cy₃SnCH₂CHCH₂ 
• 129296-32-8 tricyclohexyltin N-benzoylglycylglycinate 
• 129296-27-1 tricyclohexyltin N-benzoylglycinate 
• 96505-83-8 (cyclo-C₆H₁₁)3SnC₆H₄-p-Cl 
• 36145-48-9 (cyclo-C₆H₁₁)3SnC₅H₄N 
• 36145-49-0 3-tricyclohexylstannylpyridine 
• 36145-47-8 (cyclo-C₆H₁₁)3SnC₄H₃O 
• 2413-03-8 (4-vinylphenyl)tricyclohexyltin 

Relevant articles and documents

RECYCLING OF ORGANOTIN COMPOUNDS

A method for the synthesis of a first organic molecule, said method comprising the steps of: a) Reacting a first reactant with an organotin reactant having at least one optionally substituted organic group having from 5 to 20 carbon atoms selected from alkyl, alkenyl, alkynyl, alkoxyalkyl, alkoxy, alkylthioalkyl, carboxylates and alkylaminoalkyl groups, thereby forming a mixture of a product and a tin-containing by-product, and b) Removing most of the tin-containing by-product from said mixture in such a way as to provide a purified product comprising less than 1000 ppm of remaining tin-containing by- product, wherein said step of removing most of said tin-containing by-product is either an extraction between a first liquid and a second liquid, said second liquid being more polar than said first liquid and at least partly immiscible therewith or is a reversed phase chromatography.

HETEROGENEOUS ORGANOTIN CATALYSTS

Supported heterogeneous organotin catalysts of the formula X1, X2, or X3: wherein Z is a spacer group; Y is an insoluble phenyl-group containing copolymer; R1, R2, R3, R5, and R6 are independently selected from halogen, alkyl, alkylene, phenyl, vinyl, allyl, naphthyl, aralkyl, and Z; and R4 is alkyl, alkylene, phenyl, vinyl, allyl, naphthyl, or aralkyl.

A general route to alkylene-, arylene-, or benzylene-bridged ditin hexachlorides and hexaalkynides

The preparation of alkylene-, arylene-, or benzylene-bridged ditin hexachlorides in high yields from the reaction of the corresponding hexacyclohexylated compounds with tin tetrachloride is described. The tetragonal geometry of the tin atom of 1,4-bis(trichlorostannyl)-butane in the solid state indicates that no intramolecular or intermolecular interaction involving either end of the molecule exists in this compound. The ditin hexachlorides were successfully transformed in the corresponding hexaalkynides, precursors of hybrid materials.